2020年12月1日 · Halohydrin dehalogenases (HHDH) are industrially relevant biocatalysts exhibiting a promiscuous epoxide-ring opening reactivity in the presence of small nucleophiles, thus giving access to novel carbon–carbon, carbon–oxygen, carbon–nitrogen, and carbon–sulfur bonds.

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2012年11月1日 · Halohydrin dehalogenase (HHDH, EC 4.5.1.X), also called haloalcohol dehalogenase, halohydrin epoxidase, or halohydrin hydrogen-halide-lyase, can degrade halohydrins to their corresponding epoxides without the need of any cofactors for keeping its activity (Fig. 1; Archelas and Furstoss 1997).

These enzymes, also called halohydrin dehalogenases (HHDHs), haloalcohol dehalogenases, or halohydrin hydrogen-halide-lyases, belong to the enzyme class of lyases (EC 4.5.1.-) and catalyze the reversible dehalogenation of halohydrins with epoxide formation through intramolecular nucleophilic displacement of the halogen substituent by the neighbo...

2017年2月6日 · Halohydrin dehalogenases (HHDHs, EC 4.5.1.X), also known as halohydrin epoxidases or halohydrin hydrogen-halide-lyases, are microbial enzymes that catalyze the reversible dehalogenation of...

2016年4月6日 · Halohydrin dehalogenases (HHDHs) are remarkable enzymes with an exceptional potential for biocatalysis. Naturally, these enzymes play a key role in the bacterial degradation of halogenated compounds such as epichlorohydrin or 1,3-dichloro-2-propanol.

2020年3月10日 · Halohydrin dehalogenases (HHDHs) are valuable biocatalysts involved in the synthesis of β-substituted alcohols via their nucleophile-mediated ring-opening activity.

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