2021年4月1日 · Selective oxidation of cyclohexane (CHA) with oxygen (O 2) to product cyclohexanone (CHA-one) is an important reaction for the modern chemical industry.

2018年4月4日 · We propose that KA oil is formed via a catalytic cycle, which involves activation of the cyclohexane by a key active intermediate species, formed from the nucleophilic addition of …

2022年12月28日 · The proposed novel method involves the one-step, solvent-free oxidation of a cyclohexane/cyclohexanone (CH/CH=O) mixture, with a cheap oxidizing agent such as O 2 or …

In this study, Cu-doped mesoporous TiO 2 (Cu-MT) has been successfully synthesized via calcinating MIL-125 (Ti) doped with copper acetylacetonate, which shows high reactivity in …

2016年10月1日 · Here, we designed V 2 O 5 @TiO 2 catalysts for the selective photocatalytic oxidation of cyclohexane to KA-oil products using oxygen as an oxidant and acetonitrile/water …

2008年3月14日 · A highly efficient oxidation of cyclohexane to cyclohexanone is accomplished over phenanthroline–CuCl 2 catalyst in relatively mild conditions. This study realized nearly …

Heterogeneous oxidation of cyclohexane with tertiobutyl hydroperoxide was carried out on Pt/oxide (Al2O3, TiO2 and ZrO2) catalysts in the presence of different solvents (acetic acid …

2014年10月1日 · V–Y showed excellent catalytic activity in highly selective one-pot oxidation of cyclohexane to cyclohexanone by using tert-butylhydroperoxide as oxidant at room …

2006年5月10日 · Amongst M-ZSM-5 and M/ZSM-5 catalysts tested, Co-containing ZSM-5 (Co-ZSM-5 and Co/ZSM-5) displayed the best activity for the selective oxidation of cyclohexane to …

2024年8月30日 · Here, we demonstrate the successful oxidation of cyclohexane to cyclohexanol/cyclohexanone (KA-oil) using sol-gel encapsulated AaeUPO. Remarkably, …