2012年4月11日 · Current status and future perspectives in atom transfer radical polymerization (ATRP) are presented. Special emphasis is placed on mechanistic understanding of ATRP, …

2025年1月9日 · Atom transfer radical polymerization (ATRP) is a technique that employs the transfer of a halogen or pseudohalogen group between a catalyst and a...

2009年3月1日 · Among these techniques, cobalt-mediated radical polymerization (CMRP) distinguished itself by the high level of control imparted to the polymerization of acrylic and …

2017年7月28日 · The novel metallopolymer particles featuring a cobalt-containing shell are investigated by transmission electron microscopy (TEM), scanning electron microscopy (SEM) …

Atom transfer radical polymerization (ATRP) is an example of a reversible-deactivation radical polymerization. Like its counterpart, ATRA, or atom transfer radical addition, ATRP is a means …

Cobalt can control radical polymerization (RP) reactions by essentially three mechanisms: Catalytic chain transfer (CCT) Reversibile termination (RT), leading to the persistent radical …

ATRP is based on an inner sphere electron transfer process, (4) which involves a reversible homolytic (pseudo)halogen transfer between a dormant species, an added initiator or dormant …

2005年7月18日 · We report a new approach to ATRP, based upon fluorous biphase catalysis using cobalt (II) perfluorooctanoate as catalyst for styrene ATRP and reverse ATRP in the …

In this study, we combined the kinetic measurement and the computational simulation to build a kinetic model for the hybridization of cobalt-mediated radical polymerization (CMRP) and atom …

2008年11月25日 · Supported cobalt (II) catalyst through electrovalent bond could be applied as effective ATRP catalyst for the different types of vinyl monomers: styrene, n-butyl acrylate and …