
In(OH)BDC·0.75BDCH2 (BDC = Benzenedicarboxylate), a Hybrid …
2005年10月7日 · The compound In(OH)BDC·0.75BDCH 2 (BDC = benzenedicarboxylate), 1, has been synthesized and characterized by single-crystal X-ray diffraction. The structure comprises two distinct sublattices formed by a covalently linked In(OH)BDC lattice and ordered chains of hydrogen-bonded H 2 BDC molecules and can be described as a hybrid inorganic ...
A representative structure of the MX(bdc) family of compounds.
AlF (bdc), bdc = 1,4-benzenedicarboxylate, a new member of the family of MX (bdc) compounds has been synthesized under solvothermal conditions. It is formed without H...
AlF·1,4-benzenedicarboxylate: synthesis and absorption properties
AlF (bdc), bdc = 1,4-benzenedicarboxylate, a new member of the family of MX (bdc) compounds has been synthesized under solvothermal conditions. It is formed without H 2 bdc in the channels and substantial absorption capacity is observed in its as-synthesized form.
Synthesis and spectroscopic characterization of Fe3+-BDC metal …
2023年1月15日 · This work presents synthesis and spectroscopic characterization of a new metal-organic framework (MOF). The compound Fe-BDC-DMF was synthetized by the solvothermal method and prepared via a reaction between FeCl 3. 6H 2 O and benzene-1,4-dicarboxylic acid (H 2 BDC) or terephthalic acid using N,N-dimethylformamide (DMF) as solvent. The powder ...
BDC Ligand Summary Page - RCSB PDB
2001年10月12日 · Users can perform simple and advanced searches based on annotations relating to sequence, structure and function. These molecules are visualized, downloaded, and analyzed by users who range from students to specialized scientists.
the new compound In(OH)BDCâ0.75H2BDC 1 in single-crystal form. Several other indium compounds with BDC ligands have been reported previously. For example, in InH(BDC)2,6 the indium atoms are eight-coordinated by oxygen atoms from three chelating carboxylates, whereas in In2(OH)3(BDC)1.5,7 the In atoms are six-
AlF.1,4-benzenedicarboxylate: synthesis and absorption properties
2010年2月21日 · AlF(bdc), bdc = 1,4-benzenedicarboxylate, a new member of the family of MX(bdc) compounds has been synthesized under solvothermal conditions. It is formed without H(2)bdc in the channels and substantial absorption capacity is …
由m-BDC(m-BDC = 1,3-苯-二羧酸盐)构建的两种异金属金属有 …
通过单晶X射线衍射、X射线粉末衍射、ICP、TGA、IR和光致发光光谱对化合物进行了表征。 晶体结构由 X 射线衍射确定,并通过全矩阵最小二乘法精制至 R = 0.0221 和 wR = 0.0579,使用 1925 次反射,I > 2σ (I) 为 1;并且 R = 0.0654 和 wR = 0.1591 使用 1881 次反射,其中 I > 2σ (I) 为 2。 它们的框架由 M-O-C(M = Na,Cd 和 Co) 链由交替的六配位 Na (I) 中心和四配位 Cd (II) 或 Co (II) 中心组成。 这些链通过 m-BDC 进一步连接,形成不寻常的 3D 开放框架结构。
New synthesis pathway and stability study of Sr-BDC …
2023年7月31日 · Sr-BDC metal–organic frameworks (MOFs), composed of strontium ions and terephthalic acid residues, were synthesized using a simple solvothermal process without elevated pressure. This method is easily scalable and does not require special equipment. In the course of this work, the optimal synthesis temperature for this process was studied.
In(OH)BDC.0.75BDCH2 (BDC = Benzenedicarboxylate), a hybrid
2005年11月2日 · The compound In(OH)BDC.0.75BDCH2 (BDC = benzenedicarboxylate), 1, has been synthesized and characterized by single-crystal X-ray diffraction. The structure comprises two distinct sublattices formed by a covalently linked In(OH)BDC lattice and ordered chains of hydrogen-bonded H2BDC molecules and can …