The scope of Pd-catalyzed synthesis of N-Boc-protected anilines from aryl bromides and commercially available tert-butyl carbamate is described. For the first time, this process can be …

New, stable amino-protecting reagents, Boc-DMT and Fmoc-DMT, were prepared, and found to be useful for the introduction of Boc and Fmoc groups into amines. Both the reagents can …

The tert-butyloxycarbonyl protecting group or tert-butoxycarbonyl protecting group [1] (BOC group) is an acid-labile protecting group used in organic synthesis. The BOC group can be …

A one-pot tandem direct reductive amination of aldehydes with primary amines resulting in N-Boc secondary amines using a (Boc) 2 O/sodium triacetoxyborohydride (STAB) system is reported. …

2018年6月7日 · Carbamates are useful protecting groups for amines. They can be installed and removed under relatively mild conditions. One of the most common carbamate protecting …

Boc protects amines as less reactive carbamates in organic synthesis, and is deprotected with acid. Learn about examples and mechanisms here!

2016年8月26日 · In the present investigation, a very simple method and green protocol is reported for a catalyst and solvent-free BOC protection of amines. This methodology is highly efficient …

2006年10月23日 · A facile and versatile method for the chemoselective Boc protection of amines has been developed by a treatment with (Boc) 2 O in the presence of sulfonic-acid …

The Boc group is the most used protection of amino groups for example in the synthesis of peptides, but let’s also discuss the phenylmethoxycarbonyl group (abbreviated carbobenzoxy …

In keeping with this philosophy, we report a very simple and highly efficient synthesis method for the protection of amines with BOC anhydride under catalyst and solvent-free conditions.