In this study, three excellent yellow emissive Cu () complexes were synthesized, namely [Cu), [Cu), and [CuCl (bipy) (POP)]·CH) [bipy = 4,4′-bipyridine, POP = bis (2-diphenylphosphino-phenyl)ether]. The synthesis and characterization of three complexes are introduced.

The optimized geometry of the Co@BiPy-POP clearly reveals the presence of out-of-plane Co-single atomic sites in the porous backbone. This novel photopolymer Co@BiPy-POP shows extensive π-conjugations followed by impressive light harvesting ability and is utilized for photochemical CO 2 fixation to value-added chemicals.

2019年9月19日 · 该研究组利用四 (4-溴甲基苯基)甲烷与4,4’-联吡啶在110ºC下于N-甲基吡咯烷酮中聚合，一步反应制备了高稳定性的多孔有机聚合物bipy-POP，并将其应用于催化脱溴偶联反应中。

A new heteroleptic complex formulated as [Ag (I) (Bipy) (POP)]BF 4 (Bipy = 2,2′-bipyridine; POP = bis [ (2-diphenylphosphino)phenyl]ether) was synthesized and characterized by NMR and X-ray crystallography. The complex adopts tetrahedral coordination geometry.

在此，我们报道了一种双核Cu (I)配合物， [Cu (POP) (MeCN) (4,4′-bipy)] (PF) ()，它是通过配合物 [Cu (POP) (4-PBO) (MeCN)] (PF) () 和 4,4'-bipy 配体（POP 是双 [2- (二苯基膦)苯基]醚，4,4'-bipy 是联吡啶，4-PBO 是 2 - (4'-吡啶基)-苯并恶唑)。

2019年8月16日 · Bipy‐POP exhibited high efficiency in catalyzing the reductive debromination of a variety of benzyl bromides in N, N ‐dimethylformamide with dithionite as reductive reagent. For substrates that bear electron‐donating group (s) on the benzene ring, the reactions selectively afforded dibenzyl sulfone derivatives.

A highly stable porous organic polymer bipy‐POP has been prepared from the reaction of 4,4′‐bipyridine and tetrakis (4‐ (bromomethyl)phenyl)methane in N‐methylpyrrolidone at 110 °C.

这种新型光聚合物Co@BiPy-POP表现出广泛的π-共轭，并具有令人印象深刻的光捕获能力，可用于光化学CO 2固定为增值化学品。 在叔丁基溴化铵 (TBAB) 促进剂存在下，在优化的光催化条件下，苯乙烯环氧化物 (STE) 显着转化为苯乙烯碳酸酯 (STC) (约 98%)。 基于同步加速器的 X 射线吸收光谱 (XAS) 分析揭示了多孔网络中的单原子配位位点以及金属 (Co) 氧化数 +2.16。 此外，原位漫反射光谱（DRIFTS）和电子顺磁共振（EPR）研究提供了有关关键反应中间体演化的宝贵 …

该论文介绍了一种新颖的制备方法，通过一步Friedel Craft酰化反应和后续的金属化反应制备了一种新型的光催化剂Co@BiPy-POP。 该催化剂具有优异的光吸收能力和π-共轭结构，能够有效地将二氧化碳转化为有价值的化学品。

2023年11月5日 · The optimized geometry of the Co@BiPy-POP clearly reveals the presence of out-of-plane Co-single atomic sites in the porous backbone. This novel photopolymer Co@BiPy-POP shows extensive π -conjugations followed by impressive light harvesting ability and is utilized for photochemical CO 2 fixation to value-added chemicals.