
Branch-Controlled ATRP Via Sulfoxide Chemistry
2021年8月25日 · A detailed investigation revealed that the sulfoxide-modified ATRP initiator to protect the vinyl functionality on the polymer chain was successfully utilized for the synthesis …
原子转移自由基聚合(ATRP)反应详解 - 知乎 - 知乎专栏
原子转移自由基聚合( ATRP,Atomic transfer radical polymerization ) 是可逆失活自由基聚合的一个例子。 与其对应物ATRA或原子转移自由基加成一样,ATRP 是一种利用过渡金属催化剂形 …
Polymerization behaviors and branching structural analysis of …
2024年9月1日 · In a study conducted in 2013, Huang et al. explored the polymerization behaviors and branching structures of monovinyl and divinyl monomers using atom transfer radical …
Matyjaszewski Polymer Group - Carnegie Mellon University
The ATRP of the substituted styrenes were conducted in diphenyl ether at 110 °C. [M] 0 = 4.37 M and [M] 0 :[1-PEBr] 0 : [CuBr] 0 :[bipy] 0 = 100:1:1:3. Monomers with electron-withdrawing …
Studies on the development of branching in ATRP of styrene and ...
2008年9月9日 · Branching atom transfer radical polymerization (ATRP) of styrene and acrylonitrile was attempted in the presence of divinylbenzene targeting toward soluble branched …
Modeling hyperbranched polymer formation via ATRP using …
2024年10月24日 · Hyperbranched polymers (HBPs) offer distinguishing, advantageous properties that arise from their distinctive complex topology. One of the effective approaches to the …
Hydrophilic Poly(meth)acrylates by Controlled Radical Branching ...
2024年5月29日 · Hyperbranched polymers (HBPs) synthesized via atom transfer radical polymerization (ATRP) using inimers typically exhibit broad molecular weight distributions and …
Visible‐Light‐Mediated Controlled Radical Branching …
2023年1月16日 · Hyperbranched polymethacrylates were synthesized by green-light-induced atom transfer radical polymerization (ATRP) under biologically relevant conditions in the open air.
Atom transfer radical polymerization
2025年1月9日 · Atom transfer radical polymerization (ATRP) is a technique that employs the transfer of a halogen or pseudohalogen group between a catalyst and a monomeric or...
Macromolecular Engineering by Atom Transfer Radical Polymerization
2014年4月23日 · This Perspective presents recent advances in macromolecular engineering enabled by ATRP. They include the fundamental mechanistic and synthetic features of ATRP …