2020年8月6日 · The periodic bulk structures of metal–organic frameworks (MOFs) can be solved by diffraction-based techniques; however, their non-periodic local structures—such as crystal surfaces, grain ...

Although most MOF-derived materials are in powder form, constructing 3D bulk materials such as films and monoliths has gained increasing interests. Freestanding films could be fabricated by depositing MOFs on proper substrates, such as porous graphene films, carbon cloths, and metal foils ( 117 – 120 ).

2024年8月8日 · Luo et al. developed a synthesis method to synthesize MOFs using a reaction at the interface between a zinc oxide thin film and a confining polymer coating. They achieved MOF films with Turing patterns, wrinkled configurations that show exceptional stain tolerance and mechanical properties.

2024年10月9日 · Here we demonstrate single crystal homoepitaxy of a metal-organic framework (MOF) built of zinc, acetate and terephthalate ions, that encapsulate arrays of octahedral zinc dimethyl sulfoxide...

2017年6月5日 · At the current density of 10 mA cm −2, NiFe-MOF exhibits the smallest overpotential of 134 mV, compared to other samples including Ni-MOF (177 mV), bulk NiFe-MOF (196 mV) and calcined...

2023年1月11日 · Here, we demonstrate ECTs based on highly oriented two-dimensional conjugated metal-organic frameworks (2D c-MOFs). The ion-conductive vertical nanopores formed within the 2D c-MOFs films lead to the most convenient ion transfer in the bulk and high volumetric capacitance, endowing the devices with fast speeds and ultrahigh transconductance.

2019年5月15日 · We demonstrate that by the use of this approach it is possible to obtain a high-quality potential for the periodic MOF-5 crystal using density functional theory (DFT) reference calculations of small molecular fragments only.

2024年3月15日 · 然而，导电MOF作为高温储钾负极的应用必须兼顾具备丰富的氧化还原活性位点、坚固的稳定性和高的导电性。目前开发这样的块体（Bulk）MOF材料仍面临巨大挑战。

2021年7月17日 · Metal–organic framework nanosheets (MONs) have recently emerged as a distinct class of 2D materials with programmable structures that make them useful in diverse applications. In this review, the breadth of applications that have so far been investigated are surveyed, thanks to the distinct combination of properties afforded by MONs.

2022年5月3日 · Bulk doping nickel–cobalt metal organic framework (NiCo-MOF-1:1) nanosheet arrays prepared via an one-pot hydrothermal method showed enhanced capacitive performance compared with Ni-MOF and Co-MOF alone