2020年2月1日 · Herein we demonstrate a Humidity Modulated Solvent Evaporation approach to promote the nucleation, and grow of CC3 crystals. Up to date, POCs have been synthesized via conventional room temperature (RT) approach.

2024年2月1日 · Representative POCs (crystalline cages CC3, imine-cages CC13, amorphous cages ASPOC, and other cage solids) were dissolved in volatile organic solvents, followed by coating them onto various substrates. The subsequent spinning of these cage solutions at a high speed enables the formation of thin cage films.

2025年1月1日 · Porous organic cages (POCs) represent a novel class of low-density crystalline materials that exhibit distinctive pores comparable to those observed in three-dimensional extended network materials, including metal organic frameworks (MOFs), covalent organic frameworks (COFs), and porous organic polymers (POPs).

2016年9月6日 · Our most studied POCs, CC1 and CC3, are synthesized by a [4 + 6] cycloimination reaction in which four molecules of the aldehyde 1,3,5-triformylbenzene (TFB) react with six molecules of either ethylenediamine (EDA, CC1) or 1R,2R-1,2-diaminocyclohexane (CHDA, CC3-R) (Scheme 1).

2016年1月22日 · These amorphous cage materials showed a high level of porosity and tunable gas selectivity. The Brunauer–Emmett–Teller (BET) surface area of amorphous CC3 reaches 898 m 2 g −1, which is twice the surface area of highly crystalline CC3. Amorphous POCs can also be formed from cage molecules with different geometries and vertex groups.

2021年10月25日 · 多孔有机笼（POCs）引起了极大的关注，并已广泛应用于膜分离。 在这项研究中，使用分子模拟研究了四种 POC（CC3、CC5、CC17 和 CC19）作为生物燃料（由乙醇/水混合物表示）纯化的渗透蒸发 (PV) 膜。

2020年10月1日 · In this study, we report porous organic cages (POCs) as orientation-independent synthetic water channels with both high water permeability and salt rejection. POCs are a class of discrete...

2019年12月9日 · Here we report a rapid, green, and catalyst-free method to synthesize model nano-POC CC3R and modified CC3S to tune their selectivity and to expand their applications in chiral gas chromatographic (GC) separation of many challengeable chiral alcohols.

2022年1月10日 · Here, we report the fabrication of close-packed and defect-free films of a shape-persistent imine POC, CC3, which grow at the liquid–liquid interface between water and dichloromethane (Fig. 1a)....

2024年10月14日 · Herein, a viable and highly efficient three-step PSM strategy to modify a representative POC (CC3), is presented. The modified POC, OFT-RCC36+6Br−, features a charged confined space, electron-rich heteroatom, and halide ions, exhibiting significantly enhanced iodine vapor uptake compared to the parental cage.