
Insights into the role of CuO in the CO2 photoreduction process ...
2019年2月4日 · In this work, we systematically investigate CO 2 photoreduction on CuO nanoparticles synthesized by a solvothermal method, employing different electrolytes and temperatures. The results...
Structural Transformation and Degradation of Cu Oxide …
2025年1月15日 · Here, we report the structural transformation and temporal changes in the degradation mechanism of CuO x NPs under CO 2 RR conditions by using in situ small-angle X-ray scattering (SAXS), X-ray absorption near-edge structure (XANES) spectroscopy, and ex situ microscopic analysis.
Carbonate shell regulates CuO surface reconstruction for enhanced CO2 …
2024年10月31日 · Here, inspired by drug capsules with extended-release structures, we construct a water-soluble carbonate shell on metal oxide catalysts. The shell acts as a protective coating, effectively slowing...
CuO/CeO2 Nanocomposites With p–n Heterojunction for Photocatalytic CO2 ...
2024年11月13日 · The CuO/CeO 2 nanocomposites featuring a p–n heterojunction demonstrated improved light absorption efficiency and enhanced separation and transport of photogenerated charges compared to the individual CuO or CeO 2.
Morphology and mechanism of highly selective Cu(II) oxide ... - Nature
2021年2月4日 · Nature Communications - Copper oxides (CuO) can selectively catalyze the electrochemical reduction of CO2 to hydrocarbons and oxygenates. Here, the authors study the activity and...
CuO Surfaces and CO2 Activation: A Dispersion-Corrected DFT+U …
2015年12月21日 · We show that the CO 2 molecule is activated on the CuO surfaces, with an adsorption energy of −93 kJ/mol on the (011) surface, showing exothermic adsorption, while (111) and (1 11) surfaces show comparatively weak adsorption.
Role of Cu Oxide and Cu Adatoms in the Reactivity of CO2 on …
2024年6月4日 · We investigate the interaction of CO 2 with metallic and oxidized Cu (110) surfaces using a combination of near-ambient pressure scanning tunneling microscopy (NAP-STM) and theoretical calculations.
Stabilizing Cu+ Species in Cu2O/CuO Catalyst via Carbon …
2023年12月14日 · Copper oxide nanomaterials have been suggested to be efficient for highly selective multi-carbon (C 2+) production in CO 2 reduction reaction (CO 2 RR), due to the introduction of surface Cu + species from oxide catalysts. However, the Cu + species on the catalyst surface are prone to being reduced to Cu 0 under reductive conditions during CO 2 RR.
Enhanced performance of Cu-based perovskite catalyst for CO2 ...
All samples exhibited reduction peaks corresponding to CuO and La 2 CuO 4 within the temperature range of 190–300 °C, indicating that the reduction temperature of the perovskite catalyst is within 300 °C [31]. Particularly, the reduction peak of LC showed symmetrical characteristics, implying a relatively uniform distribution of Cu species ...
N-doped carbon-supported Cu–CuO nanoparticles for …
2024年5月1日 · Value-added conversion of CO 2 using solar energy is a sustainable strategy to address the energy crisis and environmental issues simultaneously. In this work, Cu–CuO/NC catalysts were successfully prepared by a sol-gel method, and the effects of Cu doping ratio and heat treatment temperature on the catalyst properties were investigated.
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