Exploration of the Mechanism of the Activation of ClONO2 by HCl …
2000年4月27日 · The reaction between ClONO2 and solvated H3O+Cl-, as on the polar stratospheric cloud (PSC) surface, was investigated with clusters involving up to seven water …
Kinetic model for reaction of ClONO2 with H2O and HCl and HOCl with HCl ...
In this model we suggest that under high acid concentration conditions both HOCl and ClONO 2 are protonated before they react with HCl. Data for all three reactions in concentrated H 2 SO …
Research on the model reactions of ClONO2 with HCl on water …
1999年11月12日 · In polar stratospheric clouds (PSC), ClONO 2 and HCl are known as reservoir species because they can react with each other as described by the following equations: (1) …
Reaction of ClONO2 with H2O and HCl in Sulfuric Acid and HNO3/H2SO4…
1998年5月30日 · ClONO2 uptake due to reaction with H2O and with HCl in H2SO4 solutions (45−55 wt %) was investigated at 203−205 K. ClONO2 hydrolysis was also investigated on …
ClONO2和HOCl在空气-水界面反应中自发生成Cl2O的分子见解
2023年8月3日 · 北京师范大学 朱重钦团队报道了ClONO 2 和HOCl在空气-水界面反应中自发生成Cl 2 O的分子见解。 相关研究成果于2023年7月31日发表于国际顶尖学术期刊《美国化学会杂 …
Real-Time Kinetics of the Uptake of ClONO2 on Ice and in the …
1997年3月6日 · The reaction of ClONO2 with HCl was studied under pulsed, concurrent, and sequential flow conditions and was found to follow a direct mechanism. The formation of Cl2 …
The HCl+ClONO2 reaction rate on various water ice surfaces
1999年12月17日 · We have proposed an alternative mechanism involving the uptake and solvation of HCl vapor to form a liquid-like surface layer as a first step, followed by a rapid …
The gas-phase reaction of ClONO2 with hydrogen chloride
The gas-phase reaction of ClONO 2 with HCl was investigated using two large-volume environmental chambers with analysis by in situ long pathlength Fourier transform infrared …
Theoretical investigation of the reaction mechanism of ClONO2 + HCl …
2013年8月22日 · Hydrated chlorine nitrate and hydrogen chloride ClONO2·HCl·(H2O)n (n = 0-3) clusters were investigated by using the MP2/aug-cc-pVTZ level of theory to clarify the reaction …
The reaction of ClONO2 with HCl on aluminum oxide
1997年7月1日 · The chlorine activation reaction ClONO2 + HCl → HNO3 + Cl2 was investigated in the laboratory on hydroxylated α-alumina surfaces under reactant partial pressure, humidity, …
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