2022年4月1日 · The as-synthesized (Fe/Co)-BDC was characterized utilizing SEM/EDX, PXRD, FTIR, Raman, XPS and BET. Characterization reveals that (Fe/Co)-BDC particles are octahedron crystalline flexible nanoporous material with remarkable anion exchange ability.

2024年11月1日 · Compared to NF/CoBDC, NF/CoBDC@CeO 2 exhibits XPS peaks that clearly belong to Ce 3+ and Ce 4+, which also indicates the successful introduction of CeO 2 (Fig. S5 c) [13]. In addition, the O 1 s spectrum of NF/CoBDC@CeO 2 exhibits an extra V O peak upon closer inspection of the high-resolution XPS spectra displayed in Fig. S5 (d).

Integrating Nb 2 CT x into MOF significantly enhance the electrocatalytic properties. CoP/C@Nb 2 C was achieved via carbonization and phosphidation of CoBDC@Nb 2 CT x. Both CoBDC@Nb 2 CT x and CoP/C@Nb 2 CT x showed excellent OER and HER activities.

2019年11月6日 · Inspired by these aspects, we introduced various missing linkers into a layered-pillared MOF Co 2 (OH) 2 (C 8 H 4 O 4) (termed as CoBDC) to prepare missing-linker MOFs. Transmission electron...

2022年4月5日 · The XPS peak shift may be attributed to these reasons: the formation of cobalt nanoparticles which caused the microenvironment changes around the Co atom; a higher electron density of Co atoms in CoBDC-NF-NH 3 than in CoBDC-NF-air-450; or the movement of the electronic cloud caused by the electrostatic attraction between Co and N-doped carbon.

The XPS analysis predicted significant changes in the oxidation state of metal nodes for many MOFs with the presence of Ni 3+ as a dominant species in the Ni-based MOFs. Moreover, XPS spectroscopy could trace ligand decomposition and decarboxylation in trimesate and terephthalate-based MOFs, respectively.

XPS confirmed that the hybridization with Ti 3 C 2 T x did not induce the change of the oxidation states of Co species in CoBDC. Notably, the conductive Ti 3 C 2 T x NSs play a key role by altering the OER to a reaction-limited process with significantly enhanced charge transfer kinetics.

XPS spectrum of CoBDC-NF-NH 3-650, we can notice a 1.3-eV shift to higher energy compared with those peaks in CoBDC-NF-air-450. The XPS peak shift may be attributed to these reasons: the formation of cobalt nanoparticles which caused the microenvironment changes around the Co atom; a higher electron density of Co atoms in CoBDC-NF-NH 3 3 CoBDC ...

2017年7月7日 · CoBDC层负载在带负电的Ti 3 C 2 T x 纳米薄片的表面，合成得到的良好的Ti 3 C 2 T x −CoBDC界面能够实现快速充电和离子交换，同时也便于水性电解液通过催化的活性CoBDC表面。这项研究的成功实现，未来将MXenes和2D MOFs应用于能量储存方面会更多的机会。

Herein, a facile in situ growth strategy is reported for the synthesis of tightly connected 2D/2D heterostructures by coupling MXene with CoBDC nanosheets. The multifunc... [...] Interfacial...