
Early stages of covalent organic framework formation imaged in
2024年6月5日 · We observe liquid–liquid phase separation, pointing to the existence of structured solvents in the form of surfactant-free (micro)emulsions in conventional COF synthesis. Our findings show that...
Imaging of coexisting classical and non-classical oriented …
2025年3月19日 · a A sequence of in situ DFM images and a schematic showing the typical dynamics of classical crystal growth in two COF-300 microcrystals and the tip-to-tip attachment of another two COF-300 ...
2.5-dimensional covalent organic frameworks - Nature
2025年1月2日 · Here, we show COFs with 2.5-dimensional (2.5D) skeletons, which are microscopically constructed with 3D bonds but have macroscopically 2D planar shapes.
Layered 3D Covalent Organic Framework Films Based on …
2023年8月15日 · Here, we synthesize two 3D crystalline COF films. The frameworks, the ionic B-based and neutral C-based COFs, have similar unit cell parameters, which enables their epitaxial stacking in a layered 3D COF film. The film growth was monitored in real time using a quartz crystal microbalance, showing linear growth with respect to reaction time.
Covalent organic frameworks: Design principles, synthetic strategies ...
2021年6月1日 · Covalent organic frameworks (COFs) are the emerging type of organic crystalline porous materials, prepared through reticular chemistry with building blocks featuring light elements (such as C, H, O, N, or B atoms), and connected through the covalent bond and extended into two or three dimensions.
Photochemical and Patternable Synthesis of 2D Covalent Organic ...
2D covalent organic frameworks (COFs) are highly porous crystalline materials with promising applications in organic electronics. Current methods involve either on-surface synthesis (solid surface) or interfacial synthesis (liquid/liquid, liquid/gas interface) to create thin films for these applications, each with its drawbacks.
COFNet: A deep learning model to predict the specific surface …
2024年7月16日 · Prediction of experimental specific surface area of COFs based on structural images. The proposed COFNet model integrates deep learning algorithms with attention mechanism. The COFNet model innovatively accepts COF structural images and derived statistical features as hybrid inputs.
Molecular model of COF-999 (IMAGE) - eurekalert.org
The new porous material for capturing carbon dioxide, called a covalent organic framework (COF), has hexagonal channels decorated with polyamines that efficiently bind CO 2 molecules (blue and ...
CuFe alloys encapsulated in COF/MOF-derived 1D N-doped …
6 天之前 · CuFe alloys encapsulated in COF/MOF-derived 1D N-doped carbon nanofibers for boosting oxygen reduction reaction in highly efficient and durable zinc-air batteries
Covalent organic framework without cocatalyst loading for …
14 小时之前 · This study develops a nonstoichiometric covalent organic framework photocatalyst for efficient sacrificial hydrogen production from water, excelling in light absorption, charge separation, and low ...