
The role of oxygen-permeable ionomer for polymer electrolyte …
2021年8月16日 · Electrochemical characterizations of single cells and microelectrodes reveal that high power density is obtained using an ionomer with high oxygen solubility. The high solubility allows oxygen to...
Protonated phosphonic acid electrodes for high power heavy
2022年1月31日 · High-temperature fuel cells that operate above 100 °C under anhydrous conditions provide an ideal solution for heat rejection in heavy-duty vehicle applications. Here we report protonated...
Electrospun phosphonated poly(pentafluorostyrene) nanofibers as …
2023年11月5日 · The degree of phosphonation was controlled with 19 F NMR by integration of the peak at δ = −135 ppm (equals two fluorine atoms from phosphonated PPFSt) and δ = −165 ppm (equals two fluorine atoms from PPFSt). The phosphonation degree was obtained by calculating the ratio of these peaks and was determined as 66%.
干货!一文带您玩转氟核磁共振波谱(¹⁹F-NMR) - 知乎
本文我们将利用 科研用小型无液氦核磁共振波谱仪-NMR,带您深入了解 氟核磁共振波谱 (¹⁹F-NMR)。 什么是氟核磁共振 (¹⁹F-NMR)? 与氢 (¹H)核磁共振相似,氟-19 (¹⁹F)核磁共振是化学实验室常用的一种分析技术,只是氟 (¹⁹F)核磁共振是测量氟-19 (¹⁹F)原子的。 研究人员可以通过这项技术来更多的了解含有氟的各种化合物。 我们能从氟核磁共振 (¹⁹F-NMR)中了解到什么? ¹H、¹³C、¹⁹F等的自旋量子数均为1/2,它们的原子核皆为电荷分布均匀的自旋球体。 所以¹⁹F和¹H一 …
Preparation of poly(styrenesulfonic acid) grafted Nafion with a …
Solid samples were grounded with dry KBr powder and pelleted for measurements taken in the wavenumber range of 400–4000 cm−1. 19F nuclear magnetic resonance (NMR) measurements were taken with a Brüker AVANCE 500 NMR Spectrometer (500 MHz).
High‐Throughput Electrospinning of Unmodified and Aminated …
2024年10月29日 · This study demonstrates a high-throughput fabrication of fiber interlayers for proton exchange membranes based on poly (pentafluorostyrene) (PPFSt) and its aminated derivatives. The fibers are produced by electrospinning, where …
A comprehensive study on the ionomer properties of PFSA …
2023年3月5日 · For instance, a possible way to measure water diffusion is nuclear magnetic resonance (NMR) spectroscopy, which has been applied to PEMs several times [28, 29]. Other methods that have been used are X-Ray scattering as well as neutron scattering.
The F/S atomic ratios (measured with wide-scan XPS) of pristine Nafion and the prepared Nafion products (MWCNT-Nafion and Nafion-Br(the sample obtained from the halogen-exchange reaction of ATRP)) to examine the breaks of C-O and C-S linkages of Nafion chains (degradation reaction Nafion) in ATRA/ATRP reactions.
Use of paramagnetic 19 F NMR to monitor domain movement in …
2020年6月8日 · Here we describe a novel 19 F-NMR spectroscopy approach to probe dynamics of large membrane proteins. We labeled a glutamate transporter homolog with a 19 F probe via cysteine chemistry and...
Nafion D2020-科学材料站 SCI Materials Hub
Chemours (formerly DuPont) Nafion PFSA polymer dispersions are made from chemically stabilized perfluorosulfonic acid (PFSA) / polytetrafluoroethylene (PTFE) copolymer in the acid (H+) form, and are available in several polymer content and dispersant compositions.