
A merged copper(I/II) cluster isolated from Glaser coupling
2019年10月24日 · Ubiquitous copper-oxygen species are pivotal in enabling multifarious oxidation reactions in biological and chemical transformations. We herein construct a macrocycle …
ACS Catalysis:三核铜簇催化剂转化,酸性电解质中合成C2产物
近日, 南京师范大学刘江 和 兰亚乾 等通过将 吲唑配体 与铜盐结合,构建了一个超稳定的 三核铜基团簇化合物 {Cu3 (μ-Inz)3} (Inz-Cu3,Inz=吲唑),该化合物在强酸碱环境中表现出高疏水性 …
Scalable synthesis of Cu clusters for remarkable selectivity control …
2023年2月27日 · Herein, we report a facile and practical approach for scalable synthesis of stable supported Cu cluster catalysts. This method involves the atomic diffusion of Cu from the …
N and OH-Immobilized Cu3 Clusters In Situ Reconstructed from …
2024年1月3日 · In situ X-ray absorption and Raman spectroscopy analyses reveal the dynamic reconstruction of nitrogen and hydroxyl-immobilized Cu 3 (N,OH-Cu 3) clusters derived from …
APCB: 亚纳米尺度Cu3金属团簇抗菌催化材料研究取得新进展 - 课 …
2021年11月29日 · 密度泛函理论(DFT)计算结果表明(图2),亚纳米尺度原子级分散且完全暴露的Cu 3 团簇作为活性中心有利于O 2 的吸附,从而促进催化O-O键断裂形成活性氧物质 …
Structural and Spectroscopic Characterization of Copper(III) …
2023年3月27日 · In this study, we synthesized Cu (II) (1) and Cu (III) (3) complexes supported by a bisamidate–bisalkoxide ligand consisting of an ortho -phenylenediamine (o-PDA) scaffold …
上海有机所Science:合成稳定Cu(III)产物,揭示铜催化偶联机理- X …
2023年10月1日 · 机理研究表明离子型和中性Cu (I)配合物的氧化加成是通过两种不同的途径进行:其中离子型配合物主要通过SN2型过程进行,次要途径是卤原子转移(XAT)过程;而中性 …
Well-defined organometallic Copper(III) complexes: Preparation ...
2021年9月1日 · In this review, the preparation and characterization of four types of well-defined copper (III) complexes including copper (III) complexes without copper-carbon bond, …
Insights into the structures and electronic properties of Cu
2017年5月2日 · By using the swarm intelligence based CALYPSO method on crystal structural prediction, we have explored the structures of neutral and charged Cu n+1 and Cu n S (n = …
Electrochromic electrically conductive Cu3 (HHTP)2 films with ...
2023年12月29日 · In this study, triphenylene-based electrically conductive MOF films were prepared and they underwent a reversible blue-to-yellow electrochromic process in diverse …
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