Flynn-Wall-Ozawa （FWO） 方程提供了一种无模型方法，通过绕过对假设反应模型的需求来提供更大的灵活性。 本研究使用 FWO 方法研究了吡蚜酮二水合物的热分解动力学，并强调了线性拟合方法的局限性。

2022年3月1日 · The kinetics and thermodynamics of biomass pyrolysis are crucial to exploring the reaction mechanisms of biomass pyrolysis and the way forward to design, optimize, and commercialize the processes. The FWO and KAS isoconversional methods and the Kissinger method were usually used to determine the activation energy and frequency factor, respectively.

2024年9月15日 · The average values estimated for activation energy by the Friedman, FWO, KAS, and Kissinger methods were 132.03, 121.65, 118.14, and 155.85 kJ/mol, respectively. The Friedman, FWO, and KAS methods showed variations throughout pyrolysis, but Kissinger’s method showed no changes.

小泽-弗林-沃尔分析法是 无模型（等转化）动力学分析方法 计算 不同恒定加热速率 β 的动态实验 中活化能 E (α) 与 转化率 α 的 关系 。 由于 无模型方法的限制，因此有必要 检查这种无模型方法是否可以使用和适用。 小泽-弗林-沃尔分析法属于积分无模型方法，首先必须求出主要动力学方程 (1) 的积分，然后取对数。 小泽-弗林-沃尔分析的积分和对数： 公式 2 的道尔近似值具有线性依赖性： 在哪里？ 如果转换程度相同的点（等转换点）取自在不同加热速率下进行的实验，那么 …

2016年2月1日 · Pyrolysis process of RDF was modelled by four reaction steps (190–340, 350–460, 470–680 and 690–890 °C) with the best possible reaction orders as 1.5th for the first three and 1st for the fourth reaction. In addition, Friedman, KAS and FWO as model-free methods were used to investigate the RDF decomposition.

2022年9月7日 · Iso-conversional models, such as Friedman, FWO, KAS, and Starink–Popescu, make it possible to predict the Ea as a function of the degree of mass conversion (α), independently of the multiple temperature programs utilized to obtain data on the heating speed (β) at a constant degree of conversion.

目前，有很多研究者使用以上方法进行固相反应热分析动力学的研究 12 - 18。 其中Flynn-Wall-Ozawa (FWO)法的使用率在所有等转化率法中占比高达80% 19。 但是传统的等转化率方法在计算活化能时有很大的误差。

Four equal conversion rate methods, which are Friedman method, Vyazovkin method, modified Coats-Redfern method and Flynn-Wall-Ozawa（FWO） method, are employed to calculate the kinetics parameters of CaCO3 decomposition.

2019年9月11日 · Three gonococcal isolates from patients with pharyngeal infection were exposed to the mouthwashes for a duration ranging from 30 seconds to 60 minutes. Isolates were then plated onto blood agar (5% horse blood) and incubated for 24 hours (5-7% CO 2, 35 ± 2°C). Growth of N. gonorrhoeae was scored on a five-point scale (0 to 4).

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