Germanium tetrachloride is a colourless, fuming liquid [4] with a peculiar, acidic odour. It is used as an intermediate in the production of purified germanium metal. In recent years, GeCl 4 usage has increased substantially due to its use as a reagent for fiber optic production.

2007年6月1日 · [SbHg 2]GaCl 4 is a new compound forming red, transparent, air sensitive crystals with a cationic network [SbHg 2] + topologically related to cristobalite. Tetrahedral (GaCl 4) − groups are located in suitable cavities.

1989年12月1日 · Anodic oxidation of highly oriented pyrolytic graphite (HOPG) in LiMCl 4 CH 3 NO 2 medium with M Al, Ga leads to the formation of graphite intercalation compounds (GICs) of average formula C 17n+ MCl 4− (CH 3 NO 2) 2.5. Different stages n ⩾ 2 have been obtained and identified by X-ray diffraction studies.

Two new inorganic supramolecular compounds, (Hg11P4)(GaCl4)4 (1) and (Hg3AsS)(GaCl4) (2), have been prepared by the solid-state reactions. Their structures are characterized by mercury-containing cationic hosts and discrete (GaCl4)− guests, which …

2022年10月1日 · It was revealed that dissociation of GaCl 4- and HCl 2- anions into Ga 3+, Cl - and H + ions at the stripping/membrane phase interface play an important role in driving the mass transfer of GaCl 4- from the concentrated hydrochloric acid solutions towards stripping phases.

1997年6月1日 · A new [ (CH 3) 2 NH 2]GaCl 4 crystal of the family of alkylammonium halogenogallates (III) was grown. X-ray studies showed that the crystals were orthorhombic, space group Pmcn. The lattice consists of (CH 3) 2 NH 2+ cations and isolated GaCl 4− anions.

Convenient Access to Gallium (I) Cations through Hydrogen Elimination from Cationic Gallium (III) Hydrides. Inorganic Chemistry 2019, 58 (18) , 12441-12445. https://doi.org/10.1021/acs.inorgchem.9b02136.

2007年8月28日 · [SbHg2]GaCl4 is a new compound forming red, transparent, air sensitive crystals with a cationic network [SbHg2]+ topologically related to cristobalite. Tetrahedral (GaCl4)− groups are located...

CsGaCl4: Crystal data, experimental conditions and details of structure refinement. Correlation of Zero Field Splittings and Site Distortions. VII. FeCl4- in CsGaCl4 with Crystal Structure...

2010年5月12日 · Tetra- n -butylammonium salts of Ga, Ga and have been prepared from stoichiometric amounts of GaX 3 and Bu 4 NX in methanol. Their crystal structures have been determined by single crystal X-ray diffraction.