Galactose oxidase (D-galactose:oxygen 6-oxidoreductase, D-galactose oxidase, beta-galactose oxidase; abbreviated GAO, GAOX, GOase; EC 1.1.3.9) is an enzyme that catalyzes the …

Galactose oxidase is the best-characterized member of the small family of radical copper oxidases that contain a stable tyrosyl radical coordinated to a single copper atom. With …

2015年10月1日 · Galactose oxidase (EC 1.1.3.9) is a single copper metalloenzyme, having a molecular weight of 65–68 kDa. Galactose oxidase catalyzes the oxidation of primary alcohols …

2015年10月8日 · Galactose oxidase (GOase) has been shown to be a promising biocatalyst for the oxidation of primary and secondary alcohols to their corresponding aldehydes and …

Galactose oxidase (GAO) is a fungal secretory enzyme that catalyzes the oxidation of a range of primary alcohols to the corresponding aldehyde, with reduction of dioxygen to hydrogen …

Galactose oxidase is a fungal secretory enzyme that catalyzes the oxidation of a primary alcohol to the corresponding aldehyde, coupled with the reduction of dioxygen to hydrogen peroxide. It …

The free radical-coupled copper catalytic motif has emerged as the unifying feature of a new family of enzymes, the radical copper oxidases. Their highly evolved active sites include a …

2023年11月30日 · In the field of alcohol oxidation, galactose oxidase (GOase) is one of the most established enzymes capable of this important chemical transformation under benign …

Density functional methods, alone and together with molecular mechanics, are used to study the catalytic mechanism of galactose oxidase. This enzyme catalyzes the conversion of primary …

2015年12月18日 · EPR spectroscopy and crystallographic analysis confirm a common active-site structure vis-à-vis the archetypal galactose 6-oxidase from Fusarium graminearum. Strikingly, …