2024年9月3日 · If a simple hydrolysis occurs by addition of HX2O H X 2 O molecule, then an unstable intermediate, carbamic acid is formed, which decomposes into the primary amine and …

2O mechanisms are characterized for the formation of carbamate and imidic acid. The second step of these two pathways exhibits the largest barrier and presents no clear pattern with …

Our results affirm that hydrolysis can occur across both the N C and C O bonds of HNCO via concerted mechanisms to form carbamate or imidic acid with ΔH 0K barrier heights of 38.5 …

2012年9月24日 · The hydrolysis of isocyanate is a reaction of interest for the polymer industry, the pharmaceutical industry, and agriculture. The hydrolysis of the amidine derivatives and …

1998年9月17日 · A kinetic and mechanistic investigation of the catalyzed hydration of isocyanates was undertaken. Both experimental and theoretical results showed that the hydrolysis reaction …

Hydrolysis of N-Sulfinylamines and Isocyanates: A Computational Comparison. The Journal of Physical Chemistry A 2007, 111 (42) , 10824-10833. https://doi.org/10.1021/jp075210d

Experimental and Theoretical Evidence for a Concerted Catalysis by Water Clusters in the Hydrolysis of Isocyanates. The Journal of Organic Chemistry 1998, 63 (20) , 6867-6877. …

2017年10月1日 · According to Baker and Gaunt [7], the following mechanism is suggested for the DMF catalyzed reaction of isocyanate with water: first, the DMF molecule forms an …

2024年7月15日 · Bimolecular radical addition and H-abstraction reaction pathways are deemed the most kinetically and thermodynamically favorable mechanisms. The primary transformation …

2021年9月14日 · Our results affirm that hydrolysis can occur across both the N [double bond, length as m-dash]C and C [double bond, length as m-dash]O bonds of HNCO via concerted …