1991年1月18日 · We have chosen the Na+ICH3 NaI+CH3 and CH3-1- H2 ~CH4+H reactions which are believed to take place via a direct mechanism (subpicosecond time-scale). The reaction model and calculation method, including the potential energy surfaces, are described in sections 2 and 3, respectively.

1990年9月15日 · The effect of reagent rotational excitation on the dynamics of the Cl+ICH 3 →ClI+CH 3 reaction has been investigated using both the classical trajectory method and a statistical model, based on the RRK formalism, which …

1971年7月16日 · Reactions of the methyl compound FeI (CH3) (CO)2 (PMe3)2 carbonylates very easily, for on bubbling carbon monoxide through the n-hexane solution of the compound at 250, the reverse of reac- tion (2) occurred with formation of the acetyl compound.

Recently, good agreement was found between experimental and phase space theory (PST) results concerning the recoil energy and angular distributions in the products of the reactions O (1D, 3P)+ICH3→OI+CH3. The details of the calculations are presented in this work. Three models are proposed which assume diff

1990年11月1日 · Differential and total reaction cross sections for the Cs+ICH 3 →CsI+CH 3 system have been measured as a function of the collision energy by using the crossed beam technique.

Differential reaction cross-sections for the Cs + ICH→ CsI + CH system have been measured as a function of the collision energy using a simple molecular-beam apparatus. A new oven design suitable for producting stable beams of highly reactive metals was used to produce a Cs beam the (oven) chemical reaction Ba (s)+

The effect of reagent rotational excitation on the dynamics of the reactions Na + ICH 3 and F + ICH 3 has been investigated using classical trajectory methods. Both reactions have similar reagent mass ratios, but very different potential–energy surfaces.

2007年10月26日 · A three-body direct interaction model is used to calculate angular and kinetic energy distributions for the products of the K + ICH 3 → KI + CH 3 reaction. Experimental distributions can be rationalized consistently in terms of the model if the CH 3 -I interaction is dependent on the orientation of CH 3 I with respect to the incoming K atom.

Differential reaction cross-sections for the Cs + ICH3→ CsI + CH3 system have been measured as a function of the collision energy using a simple molecular-beam apparatus.

The effect of reagent rotational excitation on the dynamics of the reactions Na + ICH3 and F + ICH3 has been investigated using classical trajectory methods. Both reactions have similar reagent mass ratios, but very different potential–energy surfaces.