Polymer-grafted metal–organic frameworks: design, synthesis, and ...
In summary, ATRP is a powerful technique to graft polymers from MOF surfaces. ATRP not only precisely controls molecular weight, but also is tolerant of a wide range of functional groups. …
A Cu(ii) metal–organic framework as a recyclable catalyst for ARGET ATRP
A Cu(ii) MOF can serve as an efficient catalyst for activators regenerated by electron transfer atom transfer radical polymerization (ARGET ATRP), e.g. for the synthesis of poly(benzyl …
Metal‐Organic Frameworks in Polymer Science: Polymerization …
MOFs as polymerization catalysts for reversible deactivation radical polymerization (RDRP), photopolymerization, and coordination polymerization will be addressed. Moreover, the review …
Confining CsPbI3 perovskite in metal organic framework (MOF …
2024年10月1日 · In this study, a binary synergistic hybridization strategy was successfully applied to near infrared (NIR) light-induced ATRP system with a highly efficient, stable, and reusable …
Reciprocal regulation between MOFs and polymers
2022年9月1日 · For example, [Cu 2 (bdc) 2 (ted)] n was used as a redox catalyst in an atom transfer radical polymerization (ATRP), where the catalyst reversibly activated the …
Mn-MOF catalyzed multi-site atom transfer radical polymerization ...
A green electrochemical biosensor was developed based on metal-organic framework (MOF)-catalyzed atom transfer radical polymerization (ATRP) for quantifying miRNA-21, used as the …
A generalizable method for the construction of MOF@polymer …
2018年12月12日 · We report a generalizable approach to construct MOF@polymer functional composites through surface-initiated atom transfer radical polymerization (SI-ATRP). Unlike …
一种通过表面引发的原子转移自由基聚合构建 MOF@polymer 功能 …
我们报告了一种通过表面引发的原子转移自由基聚合 (SI-ATRP) 构建 MOF@polymer 功能复合材料的通用方法。 与需要将引发基团共价预锚定在基材表面上的传统 SI-ATRP 不同，在我们的 …
将 CsPbI3 钙钛矿限制在金属有机框架 （MOF-545） 中作为稳定的 …
已在 cspbi3@mof-545（10 %） 催化的光 atrp 系统中证实了强耐氧性。 在大容量光 ATRP 系统 （100 mL） 中，使用空气中的近红外光，甲基丙烯酸甲酯 （MMA） 的聚合在 10 小时内实现 …
A visible-light photoinduced controlled radical polymerization …
2023年11月10日 · In this paper, we investigated Fe(III)-based MOF, MIL-100(Fe), as a heterogeneous photocatalyst for photo-ATRP of several methacrylate and acrylate monomers …