
Metal–Organic Network-Forming Glasses | Chemical Reviews
2022年1月19日 · We elaborate on the criteria for classifying CP/MOF glasses and comprehensively discuss the three common strategies employed to obtain a glassy state. We …
Highly porous metal-organic framework liquids and glasses via
2024年5月24日 · By combining the porosity of crystalline metal-organic frameworks (MOFs) with the unique processability of the liquid state, melt-quenched MOF glasses offer exciting …
Melt-quenched carboxylate metal–organic framework glasses
2024年2月8日 · In this study, we present the example of carboxylate-based melt-quenched MOF glasses comprising Mg2+ or Mn2+ with an aliphatic carboxylate ligand, adipate.
Glass formation, structure, relaxation, and property of metal …
2025年2月1日 · Metal-organic framework (MOF) glasses have emerged as a novel fourth class of inorganic-organic hybrid glasses, separate from traditional inorganic, organic, and metallic …
Nanoporous Transparent MOF Glasses with Accessible Internal …
2016年8月18日 · Here, we present a generalizable chemical strategy for making such MOF glasses by assembly from viscous solutions of metal node and organic strut and subsequent …
Melt-Quenched Glasses of Metal–Organic Frameworks
2016年2月17日 · The MOF-glasses formed upon heating above T m and cooling maintain the extended framework connectivity reminiscent of the crystalline MOF state, though in a long …
Through the MOF looking glass - Nature Materials
2023年12月20日 · Processible centimetre-scale porous glasses using zeolitic imidazolate framework (ZIF) materials are developed, while fine-tuning of the processing conditions allows …
熔融后还能形成多孔结构?新型MOF玻璃- X-MOL资讯
2019年4月14日 · 金属有机框架(MOF)是当前材料领域的一个研究热门,到目前为止有形形色色近6万种MOF被报道,它们在气体吸附和分离以及催化方面的潜力被广泛看好。 众所周 …
Large‐Area Metal–Organic Framework Glasses for Efficient X‐Ray ...
2024年11月17日 · Semiconductive metal–organic framework (MOF) glass films are known for their remarkably smooth surface morphology, straightforward synthesis, and capability for …
High-Porosity Metal-Organic Framework Glasses - Wiley Online …
2023年2月15日 · We report a synthetic strategy to link titanium-oxo (Ti-oxo) clusters into metal-organic framework (MOF) glasses with high porosity though the carboxylate linkage. A new …