
Construction of hierarchically porous metal–organic ... - Nature
2017年5月25日 · We demonstrate that linker labilization method can create controllable hierarchical porous structures in stable MOFs, which facilitates the diffusion and adsorption …
Hierarchical metal-organic framework (MOF) pore engineering
2022年1月1日 · The design of larger pores or hierarchical pores broaden MOF applications to the recognition of larger molecules. Meanwhile, precisely-controlled pore structure and …
Metal–organic frameworks: Structures and functional applications
2019年7月1日 · Metal–organic frameworks (MOFs), also known as porous coordination polymers (PCPs), are constructed by organic linkers and metal ions or clusters and have emerged as a …
Tuning MOF/polymer interfacial pore geometry in mixed matrix
2024年7月10日 · In this quest, combining a high-selective ultrasmall pore one-dimensional (1D) channel MOF with a highly permeable polymer offers a unique opportunity to engineer an …
Pore Engineering in Metal–Organic Frameworks for Enhanced …
2025年1月8日 · Metal–organic frameworks (MOFs) are emerging as ideal porous materials for hydrocarbon separation due to their exceptional porosity and structural tunability.
Characterization of Pore Structure in Metal−Organic Framework …
2007年11月29日 · MOF-5-like crystals were studied by small-angle X-ray scattering (SAXS) to reveal, both quantitatively and qualitatively, their real structural details, including pore surface …
Metal-organic framework functionalization and design …
2019年7月26日 · Metal-organic frameworks (MOFs) are a class of porous materials with unprecedented chemical and structural tunability. Their synthetic versatility, long-range order,...
Recent advances in customizing the electrostatic potential pore ...
2025年3月21日 · Therefore, MOF adsorbents featuring negative pore environments will selectively adsorb C 2 H 2 through complementary electrostatic interactions while effectively …
2020年1月10日 · The pore chemistry of MOFs is articulated in terms of site isolation, coupling, and cooperation and relate that to their functions in guest recognition, catalysis, ion and …
Creating hierarchical pores in metal–organic frameworks via
2022年10月28日 · It is challenging to create an appropriately large pore size while avoiding framework collapse in MOFs. Herein, we present the generation of mesopores in microporous …