1984年1月1日 · Na 2[Ru(NO)(NO 2)4(0H) ].2H20 is a useful reagent for preparing other nitrato- or nitro-(nitrosyl)derivatives, reacting with 8 HN0 3 to give [Ru(N0)(N0 3) 3(H 20) 2] [874], with concentrated aqueous ammonia to give [Ru(NO)(N0 2) 2(NH 3) 2(CH)] [1899], with dilute perchloric acid to give [Ru(NO)(NO 2) 2(H 2O) 2(0H) ] [319], and with HX 1117 OH ...

Electrocatalytic NO 2 – reduction to NH 3 (NO 2 RR) presents a prospective approach to mitigate contaminate NO 2 – and produce valuable NH 3 simultaneously. Herein, single-atom Ru supported on MoS 2 (Ru 1 /MoS 2) is developed for effective and robust NO 2 RR.

Light-induced Ru-NO bond dissociation in solution may involve transient linkage isomers MS1 (Ru-ON) and MS2 (Ru-η 2 -NO), which can be detected spectroscopically and analyzed computationally.

2023年11月6日 · These single-atom Ru active sites demonstrate remarkable thermal stability and enhance the activation efficiency of reactants (NO and O 2). The Ru 1 /CeO 2 catalyst, with Ru single...

84 Ru(II)‒NO +, is dominated by strong π-back-bonding between Ru 85 dπ + orbitals and π* orbitals of NO , which is consistent with the 86 thermodynamic and kinetic stability of NO with regard to

2016年10月18日 · In this article, density functional theory in conjunction with Monte Carlo statistical mechanical simulation was used to investigate the electronic structure, reduction potential, solvation, and solvent effects on the electronic spectra of nitrosyl ammine complexes using [Ru (NH 3) 5 (NO)] 2+/3+ as model compounds.

In this piece of research we elucidate the nature of the Ru–NO and Ru–NO 2 bonding in a cis-[Ru(NO)(NO 2)(bpy) 2] 2+ complex energy decomposition (Su–Li EDA) and topological (e.g., QTAIM) and natural bond orbital analysis. It was observed that the strength of these bonds is directly correlated with the relative stability of isomers ...

Ruthenium (III) nitrosyl nitrate solution is a stable and water-soluble compound. The presence of the nitrosyl ligand contributes to its distinct reactivity and coordination behavior. Additionally, the compound exhibits characteristic spectroscopic properties that make it valuable in analytical and research applications.

1983年1月1日 · Ru (NO) 2 L 2 (L = PPh 3) is oxidized in acetonitrile at a Pt electrode in an irreversible two electron process. The main cause for the activation energy is presumably linked to the slow configuration change from a pseudo-tetrahedral to a planar structure.

2015年7月1日 · A simple one-pot synthesis of RuO 2 nanoparticles by the thermal decomposition of ruthenium nitrosyl nitrate [Ru (NO) (NO 3) 3] up to 800 °C was investigated. The RuO 2 phase was characterized by XRD, SAXS, FE SEM/EDS, Raman, DTA/TGA and FT-IR techniques.