Chloride, Alkoxide, or Silicon: The Bridging Ligand Dictates the …
2024年12月3日 · We report the synthesis and characterization of a series of high- and low-spin dicobalt complexes of the tBu PNNP expanded pincer ligand. Reacting this dinucleating ligand …
Magnitude and consequences of OR ligand σ-donation on alkene …
This provides clear evidence of the decreasing σ-donating ability of the OR ligand with an increasing number of fluorine atoms and the positioning of a siloxy ligand in between OtBu F3 …
A Comparison of the Influences of Alkoxide and Thiolate Ligands …
2001年9月7日 · M2(OtBu)6 compounds (M = Mo, W) react in hydrocarbon solvents with an excess of tBuSH to give M2(OtBu)2(StBu)4, red, air- and temperature-sensitive compounds. …
Pyridine, isocyanide, carbodiimide and allene adducts of hexakis ...
1998年3月30日 · Pyridine binds more strongly to the fluoroalkoxide but the structural parameters of the compounds W2 (OCMe2CF3)6 (C6HsN)2 and W2 (OtBu)6 (4-CH~C6H4N)2 reveal an …
Figure S9. DRIFT spectrum of [Ce{OSi(OtBu)3}4K] (2). - ResearchGate
The triphenylsiloxide ligand recently allowed the isolation of molecular complexes of Tb(iv) and Pr(iv) providing an unique opportunity of investigating the luminescent...
三（叔丁氧基）甲硅烷氧基配合物作为均质氧化锆和氧化铪二氧化 …
一种异构体包含 4 配位金属中心，而另一种是 5 配位并具有螯合 η2-OSi (OtBu)3 配体。 1 到 ZrO2·4SiO2 的固态转变产生了一种开放的纤维材料，该材料有些有序，具有直径约 20 纳米的 …
Ligand accelerated catalysis can be most simply defined as any reaction where. Ligand acceleration effect (LAE) is defined by k0. Useful levels of selectivity can be achieved when …
Syntheses and Structures of Cationic and Neutral, Homo- and ...
2010年2月1日 · The cationic, trigonal-pyramidal [Zr(OtBu)3]+ moiety enforces distorted octahedral geometries on its complexes. Surprisingly, however, the anions (SnCl3)−, CF3SO3−, and …
Dimolybdenum(III) Complexes of −OSi(OtBu)3, −O2P(OtBu)2, and …
New dimolybdenum(III) complexes containing various combinations of −OSi(OtBu)3, −O2P(OtBu)2, and −OB[OSi(OtBu)3]2 ligands have been synthesized and structurally …
H-Glu-OtBu | ADC Linker | MCE - MCE-生物活性分子大师
H-Glu-OtBu is a non-cleavable ADC linker used in the synthesis of antibody-drug conjugates (ADCs). H-Glu-OtBu is also a alkyl chain-based PROTAC linker that can be used in the …