2014年12月5日 · Through a kinetically controlled synthetic process, we synthesized PCN-223, a new porphyrinic Zr-MOF constructed from the newly reported hexagonal prismatic 12-connected Zr 6 cluster through an unusual disordered arrangement, giving rise to the first example of the shp-a network in MOFs.

2017年3月29日 · A highly robust metal–organic framework (MOF) constructed from Zr6 oxo clusters and Fe(III) porphyrin linkers, PCN-223-Fe was investigated as a heterogeneous catalyst for oxygen reduction reaction ...

2020年8月10日 · Herein, we report the design of a new MOF, denoted PCN-226, which is built by linking redox-active metalloporphyrins and Zr (+4) cations. Use of earth abundant elements significantly reduces the producing cost as compared to use of noble metal-based materials.

2020年4月25日 · We propose that PCN-223 nanoparticles, a kind of MOF, may be used as potential carriers for drug delivery to the rectum for the treatment of CRC. The PCN-223 nanoparticles possess a highly porous structure, into which an anti-cancer drug, such as 5FU, can be encapsulated to serve as a depot for sustained drug release.

PCN-221 ， PCN-222， PCN-223 多孔有机骨架. 描述：采用连续沉积法，将低成本的CH3NH3PbI3 (MAPbI3)钙钛矿QDs包裹在 铁卟啉基MOF PCN-221 (Fex)的孔隙中，构建了一系列 MAPbI3@PCN-221 (Fex) (x = 0~1)复合光催化剂。 得利于PCN-221 (Fex)骨架的保护，该复合光催化剂在含水反应体系中表现出良好的稳定性。 此外，由于QDs与PCN-221 (Fex)中Fe催化位点的紧密接触，且QDs中的光生电子可以迅速转移到Fe催化位点，使得PCN-221 (Fex)光催化 …

2023年3月1日 · PCN-223 was camouflaged with phospholipid bilayers to improve the biostability and cellular uptake owing to the strong Zr–O–P chemical complexation between Zr-MOFs and phospholipid [37].

2022年7月15日 · In this work, four Zr 6 O 8-porphyrinic MOFs (PCN-223, PCN-224, PCN-225, and MOF-525) with different topologies were selected to investigate their performance and mechanisms for the removal of contaminants from hypersaline waters in a visible photocatalytic degradation system.

2014年12月24日 · Through a kinetically controlled synthetic process, we synthesized PCN-223, a new porphyrinic Zr-MOF constructed from the newly reported hexagonal prismatic 12-connected Zr6 cluster through an unusual disordered arrangement, giving rise to the first example of the shp-a network in MOFs.

基于卟啉的zr基mof（pcn-222/mof-545, pcn-223,nu-902, mof-525和pcn-138等）因其结构的高稳定性和功能的丰富性而受到广泛研究。 近年来MOF-545在气体存储、催化、药物递送等方面得到广泛研究。

1) pcn-223具有稳定的骨架结构，可负载金属催化剂或储气及吸附材料 2) PCN-223(H或M) 可在光照条件下将氧气转化为单线态氧，具有光催化有机反应的性能，可作为生物探针使用