Design of hierarchically porous Zr-MOFs with reo topology and …
2023年3月1日 · Hierarchically porous Zr-mofs (H-UiO-66-X) were synthesized through an in situ self-assembly template strategy. PMA/H-UiO-66–1 presented well-confined PMA in the …
Zr(IV) and Hf(IV) based metal–organic frameworks with reo …
2012年7月6日 · A modulator (benzoic acid) facilitates formation of an eight-connecting cluster leading to a new framework which adopts reo topology. Zr and Hf based MOFs with enhanced …
Combining Linker Design and Linker-Exchange Strategies for the ...
A Zr (IV)-based metal–organic framework (MOF), termed reo-MOF-1 [Zr6O8(H2O)8(SNDC)4], composed of 4-sulfonaphthalene-2,6-dicarboxylate (HSNDC2–) linkers and …
The reo-MOF-1 A framework was obtained by linker exchange to yield a chemically and thermally stable material despite its large pores. Remarkably, reo-MOF-1 A exhibits permanent porosity …
Reticular chemistry in the rational synthesis of functional zirconium ...
2019年5月1日 · In the past two decades, reticular chemistry has developed into a powerful tool for the design and synthesis of porous, crystalline framework materials. The discovery of the first …
Defect-Engineered Metal–Organic Frameworks - Wiley Online …
2015年6月3日 · Defect engineering in metal–organic frameworks (MOFs) is an exciting concept for tailoring material properties, which opens up novel opportunities not only in sorption and …
在具有 reo 拓扑结构的 Zr-MOF 中设计合适的孔径并结合磺酸官能 …
通过能够从水性介质中有效去除阳离子 MG 染料的溶剂热法制备了具有 reo 拓扑结构的 Zr 基金属有机骨架，表示为 Reo-MOF-1。 观察 pH 溶液、吸附剂含量、吸附等温线和动力学对 MG 捕 …
大连理工大学冯潇课题组JACS：MOF缺陷可控合成-单一类型缺陷 …
2021年12月30日 · 调控缺陷，开拓mof性能，其中控制合成是关键。 目前，MOF中观察到两种的点缺陷：配体缺陷和金属节点缺陷，即MOF两种组分缺乏带来不同类型缺陷。 目前常见的方 …
Unlocking New Topologies in Zr-Based Metal–Organic …
2023年4月26日 · This tutorial deals with the handling of MOF crystals and analysis of crystallographic data obtained from single-crystal X-ray diffraction, focusing on two features …
Rare earth metal–organic frameworks (RE-MOFs ... - ScienceDirect
2021年2月15日 · Rare earth metal–organic frameworks (RE-MOFs) have drawn a good deal of research interest due to their unique properties (e.g., luminescence, magneticity, and intrinsic …