2016年8月22日 · Here we demonstrate the first couplings of redox-active esters (both isolated and derived in situ from carboxylic acids) with organozinc and organomagnesium species …

2020年10月21日 · In view of the versatile reactivity of free thiols, here we report the development of a visible light-mediated direct decarboxylative thiolation reaction of alkyl redox-active esters …

2024年4月4日 · Here, we report a simple catalyst and reductant combination that converts two types of feedstock chemicals, carboxylic acids and olefins, into tetrasubstituted carbons …

2016年4月21日 · Redox-active esters enable the cross-coupling of alkylzinc reagents with high chemoselectivity (Fig. 2F) even in complex contexts, reminiscent of that exhibited in classic …

2021年1月20日 · The NHPI esters are predisposed to undergo reductive fragmentation via a single electron transfer (SET) process under thermal, photochemical, or electrochemical …

2022年6月10日 · Aliphatic strained rings can be (hetero)arylated through a decarboxylative cross-electrophile coupling. The keys to this advance are: 1) a new ligand that enables tolerance of a …

2020年6月3日 · In this review, we present recent advances using redox-active esters as carbon-centered radical precursors to form carbon–carbon and carbon–heteroatom bonds. The one …

2018年2月7日 · The review presented herein covers all the recent developments in the field of redox-active ester (RAE)-based cross-couplings since the initial discovery. Depending on the …

2018年2月7日 · Photoredox catalysis allows the use of alkyl redox-active esters, recently established as a superior class of alkyl electrophiles, whereas copper catalysis enables C …

2025年3月6日 · Elevated levels of reactive oxygen species (ROS) in cancer cells, arising from their altered metabolism, represent a distinctive therapeutic target. Here, we introduce the first …