tert-Butyl hypochlorite is the organic compound with the formula (CH 3) 3 COCl. A yellow liquid, it is a rare example of an organic hypochlorite, i.e. a compound with an O-Cl bond. It is a …

本文总结了在酸性介质（pH = 5-7）中相应的N-氯胺形成过程中获得的动力学结果。 动力学研究表明相对于t而言是一阶的BuOCl浓度。 相对于含氮化合物的浓度，涉及苄胺，甘氨酸和二甲胺的氯化反应均为一阶，相对于质子浓度而言约为一阶。 与2,2,2-三氟乙胺的反应更加复杂，并且相对于胺的反应顺序随pH的变化而变化。 版权所有©2014 John Wiley＆Sons，Ltd.

2014年10月6日 · The chlorination reactions of nitrogenous organic compounds (2,2,2-trifluoroethylamine, benzylamine, glycine, and dimethylamine) by tert -butyl hypochlorite (t BuOCl) were studied at 25 °C, ionic strength 0.5 M and under isolation conditions.

Know about technical details of t-BuOCl like: chemical name, chemistry structure, formulation, Pharma Intermediates, Manufacturers, Suppliers, Chemicals and more at pharmacompass.com.

Aqueous phosphoric acid is an effective, environmentally benign, selective and mild reagent for the deprotection of tert -butyl carbamates, tert -butyl esters, and tert -butyl ethers. CBZ carbamates, azetidine, benzyl and methyl esters, TBDMS, and methyl phenyl ethers are tolerated. The reactions are high yielding, and the workup is convenient.

2021年11月15日 · We have developed a new iron-catalyzed method for chlorination of aro-matic compounds using tert-butyl hypochlorite. The reactions take place with high conversion and selectivity.

在过去十几年里,通过脱羧偶联反应以及炔烃的官能化反应来构建碳-碳键和碳-杂键已引起人们越来越多的关注.这类反应具有原子经济性高,合成步骤简单,原料简单易得等特点,已成为合成天然产物及药物活性分子的有效方法.但此类反应通常需要使用昂贵的过渡金属且反应条件苛刻.所以,开发一种新型的,条件温和的,无过渡金属催化的脱羧偶联和炔烃官能化反应具有重要意义.本论文在无过渡金属条件下实现了 2-吡啶甲酸类化合物与芳烃的脱羧芳基化反应.这种新型脱羧芳基化反应具有 …

2014年12月1日 · Kinetic studies showed a first order with respect to t BuOCl concentration. The chlorination reac-tions involving benzylamine, glycine and dimethylamine were all first order with respect to...

用次氯酸叔丁酯（t-BuOCl）对甲苯进行一元氯化反应,写出这个反应的反应式.已知该反应按自由基链式反应机理进行,写出这个反应的链引发阶段与链传递阶段的反应式. t-BuOCl-光照->t-BuO.+Cl. (化学式后头加个.表示自由基) 这是链引发Cl.+CH3C6H5-->CH2ClC6H5+H.H.+Cl2--->HCl+Cl. 这两个是链传递总反应：t-BuOCl+MePh---->t-BuOH... 解析看不懂？ 免费查看同类题视频解析. 用次氯酸叔丁酯（t-BuOCl）对甲苯进行一元氯化反应,写出这个反应的反应式.已知该反应按自由基链 …

Simple, chemoselective, catalytic olefin isomerization. Catalytic amounts of Co (Sal (tBu,tBu))Cl and organosilane irreversibly isomerize terminal alkenes by one position. The same catalysts effect cycloisomerization of dienes and retrocycloisomerization of strained rings.