In TiCl 3, each titanium atom has one d electron, rendering its derivatives paramagnetic, that is, the substance is attracted into a magnetic field.Solutions of titanium(III) chloride are violet, which arises from excitations of its d-electron.The colour is not very intense since the transition is forbidden by the Laporte selection rule.. Four solid forms or polymorphs of TiCl 3 are known.

用途. 化学工业中用作合成反应的催化剂，与三乙基铝可以组成齐格勒催化剂，与一氯二乙基铝或倍半乙基铝（一氯二乙基铝和二氯乙基铝混合物）组成络合催化剂，这些催化剂可用于乙烯的聚合，丙烯聚合及橡胶异物二烯的聚合反应。

2017年5月31日 · The low-temperature structure results from rotations of the $\ce{[TiCl6]^3-}$ octahedra around a 4-fold axis. (Emphasis and square brackets mine) Source: Amels, R.; Kremer, S.; Reinen, D. Jahn-Teller effect of titanium(3+) in octahedral coordination: a spectroscopic study of hexachlorotitanate (TiCl63-) complexes. Inorg.

2025年3月7日 · ChemicalBook 致力于为化学行业用户提供四氯化钛的性质、化学式、分子式、比重、密度,同时也包括四氯化钛的沸点、熔点、MSDS、用途、作用、毒性、价格、生产厂家、用途、上游原料、下游产品等信息。

1986年1月15日 · The preparation of the newly identified double salt [PCl 4] 3 [TiCl 6][PCl 6] is described herein.Its structure is elucidated by both X-ray analysis and Raman spectrum. This compound is tetragonal, space group P4 2 /mbc with a = 14.648(1) Å, c = 13.922(1) Å, V = 2987(1) Å 3 and Z = 4, and is isostructural with the related tin compound. The structure was refined by least-squares to R = 4.3% ...

2022年11月5日 · A series of ionic complexes of composition [M. Crown] + [TiCl 5]-, where M - Li, Na, K; Crown - dibenzo-18-Crown-6, benzo-15-crown-5, dibenzo-24-crown-8 has been synthesized by the interaction of alkali metal chlorides, titanium tetrachloride and crown ethers in anhydrous toluene.Carrying out these syntheses in acetonitrile results in crystallization of complexes solvated with acetonitrile.

2001年8月1日 · [Hg 6 P 4](TiCl 6)Cl is synthesized in an ampoule at 400°C.Its crystal structure is solved on the basis of a CAD4 single-crystal experiment in a cubic space group Pa-3 (a=11.7675(6) Å, Z=4, R=0.0331).The structure is comprised of the three-dimensional cationic framework 3 ∞ [Hg 6 P 4] 4+, and two different guest anions, octahedral TiCl 3− 6 and monoatomic Cl −, trapped in the cavities ...

Explore the fluorite family crystalline lattice structure of Cs2TiCl6 with lattice parameters, 3d interactive image of unit cell, cif file, lattice constants & more.

K2TiCl6 crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. K1+ is bonded to twelve equivalent Cl1- atoms to form KCl12 cuboctahedra that share corners with twelve equivalent KCl12 cuboctahedra, faces with six equivalent KCl12 cuboctahedra, and faces with four equivalent TiCl6 octahedra.

2020年7月16日 · Cs2TiCl6 crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Cs1+ is bonded to twelve equivalent Cl1- atoms to form CsCl12 cuboctahedra that share corners with twelve equivalent CsCl12 cuboctahedra, faces with six equivalent CsCl12 cuboctahedra, and faces with four equivalent TiCl6 octahedra.