Molecular-caged metal-organic frameworks for energy …
2024年5月8日 · Ligand engineering is an efficient strategy to modulate the pore structures of MOF, for example, UiO-68 with a larger ligand ([p-terphenyl]-4,4″-dicarboxylic acid, TPDC) has …
Efficiently regulating the electrochromic behavior of naphthalene ...
2025年2月6日 · Considering that the electrochromic mechanism of NDI groups is based on the change of free radicals, we further designed and synthesized three redox active TPDC ligands …
Effect of metal coordination environment on topology of …
2014年9月1日 · Divalent metal coordination polymers with 2,5-thiophenedicarboxylate (tpdc) and bis (4-pyridylmethyl)piperazine (4-bpmp) ligands show different dimensionality and topology …
Ligand Chromophore Modification Approach for Predictive …
2023年9月12日 · TD-DFT and TD-DFPT methods were used for calculation of the optical properties of the H 2-(NH 2) 2-TPDC ligand and modified analogues and of the periodic UiO …
Switchable luminescent properties in two photochromic …
2019年9月1日 · Fortunately, we successfully synthesized two new NDI-based CPs with distinct structures, namely Zn 2 (DPNDI)(TPDC) 2 (1) and [Cd 6 (DPNDI)(TPDC) 6 (DMF) 6] (2), …
A Simple, Transition Metal Catalyst‐Free Method for the Design of ...
2023年2月15日 · To eliminate the need for expensive precious metal catalysts and possibly simplify ligand reaction protocols, we explored strategies to alter the backbone of complex …
含有aC2h-对称三联苯-3,3'-二羧酸酯接头的三维Co-和Mn-MOFs及 …
2016年9月20日 · 金属离子由四个 Ocarboxylate (η1:η1:µ2) 和两个 µ2-Odmf 原子以扭曲的八面体几何结构配位。金属中心通过桥接 3,3'-tpdc 和 dmf 配体相互连接，形成一维链。所得的一维 …
Ligand-regulated oxygen vacancies in Ti-MOFs for visible-light …
6 天之前 · Based on XPS and EPR characterization, the synthesized Ti-based MOF (Ti-H 2 TPDC) linked with bigger conjugated ligand ([p-terphenyl]-4,4″-dicarboxylic acid) with …
Genuine Pores in a Stable Zinc Phosphite for High H
2022年6月7日 · The tetradentate TIMB linker bound to zinc atoms of the isolated zincophosphite hexamers to form a 3D open-framework structure by crosslinking structural components of 1D …
含苯并噻二唑结构单元的金属有机骨架在可见光催化需氧氧化反应 …
Herein we designed and synthesized a benzothiadiazole functionalized TPDC ligand H (TPDC=terphenyl-4, 4''-dicarboxylic acid). Briefly, a Suzuki reaction of 4, 7-dibromo-2, 1, 3 …