2022年1月22日 · What is X-Ray Spectroscopy? X-ray spectroscopy is a general term for several spectroscopic techniques for the characterization of materials by using x-ray excitation. XRF works on methods involving interactions between electron beams and x-rays with samples. It is made possible by the behavior of atoms when they interact with radiation.
2024年4月3日 · X-ray spectroscopy is a powerful scientific technique that allows researchers to investigate the properties and composition of materials by utilizing X-ray radiation. It encompasses a range of spectroscopic methods that utilize the excitation of X-rays to gain insights into the atomic and molecular structure of substances.
In this experiment you will use a high resolution solid-state X-ray detector to record the characteristic spectra of several elements, repeat the pioneering work of Moseley relating X-ray energies to atomic number, and also explore the use of X-rays as a diagnostic tool for sample identification. 2. X-Ray Spectra of the Elements.
X-ray Absorption Fine-Structure (XAFS) is the modulation of the x-ray absorption coefficient at energies near and above an x-ray absorption edge. XAFS is also referred to as X-ray Absorption Spectroscopy (XAS) and is broken into 2 regimes: XANES X-ray Absorption Near-Edge Spectroscopy EXAFS Extended X-ray Absorption Fine-Structure
General definitions for the spectroscopy • X-ray Absorption Spectroscopy (XAS) is a technique for measuring the linear absorption coefficient m(E) • X-ray Absorption Fine Structure (XAFS) Terms used to define spectral regions • XANES (X-ray Absorption Near Edge Spectroscopy) or NEXAFS (Near-Edge X-ray Absorption Fine Structure)
X-ray Spectroscopy. A Critical Look at the Past Accomplishments and Future Prospects. A course presented at the Harbin Institute of Technology, December 2013. Lecture overheads. Fundamental principles of x-ray-matter interactions: x-ray absorption and emission (pdf) Principles of EXAFS and XANES data analysis (pdf)
An X-ray spectrograph consists of a high voltage power supply (50 kV or 100 kV), a broad band X-ray tube, usually with a tungsten anode and a beryllium window, a specimen holder, an analyzing crystal, a goniometer, and an X-ray detector device.
X-rays are defined as the electromagnetic radiation with a wavelength between Ultraviolet radiation and gamma radiation. The border between Ultraviolet radiation and X-rays is not clearly defined but usually set around 10-8meter, i.e. 10 nm.
How to choose the material for a soft X-ray source: 1. the line width must not limit the energy resolution; 2. the characteristic X-ray energy must be high enough to eject core electrons for an unambiguous analysis; 3. the photoionization cross section of e in different core levels varies with the wavelength of the X-ray,
suitable characteristic X-ray wavelength is crucial to obtain a strong enough photoelectron signal for analysis. 100 mm radius concentric hemispherical analyzer (CHA); vary voltages to vary pass energy. XPS: photon energy hn=200-4000 eV to probe core-levels (to identify elements and their chemical states).