
Ca 2+ -exchange in layered zirconium orthophosphate, α-ZrP: …
H + /Ca 2+ 交换机制主要由酸碱考虑触发,特别是α-ZrP/Ca 2+ -ZrP 酸碱对的pKa(评估为2.5)。 这两种化合物都是酸性化合物,内部可交换 H+ 为 α-ZrP,表面质子为 Ca 2+ -ZrP,可用作锌腐蚀的潜在抑制剂。
磷酸锆及其衍生物的离子交换性能 - 知乎
通过溶胶-凝胶法合成了一类新的离子交换剂无定形 ZrP相—四价金属酸式 (TMA)盐,TMA盐羟基H+显示了良好的质子导体性能, Cu2+、Li+与ZrP交换产生了CuZrP、LiZrP 交换相。
Layered zirconium phosphate-based artificial solid electrolyte ...
2022年3月15日 · A versatile zirconium phosphate-based artificial solid electrolyte interface on Zn metal (Zn@ZrP) is constructed by a facile spraying method. The unique layer structure and ion exchange properties of ZrP enable the formation of zinc ion channels in the interlayers of ZrP, leading to fast and stable Zn deposition kinetics on the interface of Zn@ZrP.
剥离的α-磷酸锆纳米片的组装:机制和多功能应用,Aggregate - X …
2022年2月26日 · α-磷酸锆 (Zr (HPO 4 ) 2 ·H 2O,α-ZrP)是一种无机层状化合物。 自1964年首次报道结晶α-ZrP以来,由于其合成简单和独特的理化性质,α-ZrP在机械增强、阻隔改进、阻燃、防腐、催化、环境、能源、和药。
New Applications of Zirconium Phosphate Nanomaterials
ZrP has now proven to be a promising drug nanocarrier and its unique chemical microenvironment provided by the α-type layers and the interlayer space enhances catalytic activity for numerous types of reactions.
Zirconium phosphate (ZrP)-based functional materials: Synthesis ...
2018年10月5日 · Zirconium phosphate (ZrP) and its organic derivative, zirconium phosphonate, increasingly attract research interest due to their outstanding physical and chemical properties, both in their amorphous and in their crystalline phases.
Ion‐exchange Properties of γ‐Zirconium Phosphate
2020年9月21日 · γ-Zirconium phosphate (γ-ZrP) has potential as a very useful inorganic ion-exchanger due to its stability under thermal and acidic conditions. We recently reported its facile synthesis using a modified solventless method, which could make the exploitation of its ion-exchange properties for cleanup of radioactive materials and extraction of ...
Ion-exchange properties of γ-zirconium phosphate.,Chemistry
2020年9月21日 · γ‐Zirconium phosphate (γ‐ZrP) has potential as a very useful inorganic ion‐exchanger due to its stability under thermal and acidic conditions. We recently reported its facile synthesis using a modified solventless method, which could make the exploitation of its ion‐exchange properties for cleanup of radioactive materials and ...
Ion-exchange Properties of γ-Zirconium Phosphate - PubMed
2020年11月2日 · γ-Zirconium phosphate (γ-ZrP) has potential as a very useful inorganic ion-exchanger due to its stability under thermal and acidic conditions. We recently reported its facile synthesis using a modified solventless method, which could make the exploitation of its ion-exchange properties for cleanup o …
Hierarchically Ordered α-Zirconium Phosphate Platelets in
2019年11月8日 · Platelets of α -zirconium phosphate (α -ZrP) obtained from the reflux method in H 3 PO 4 are successfully exfoliated into water via the intercalation of alkanol amines. With volume fractions...
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