
Ion Specific Effects on the Structure of Molten AF-ZrF4 Systems …
The structure of AF-ZrF 4 system (A + = Li +, Na +, K +) compounds in the liquid state is studied using an approach combining EXAFS spectroscopy with molecular dynamics simulations. A …
Influence of ZrF4 additive on the local structures and …
2024年1月1日 · ZrF 4 is preferably 8.70 mol% to maintain the comprehensive performance of molten mixture. Molten NaF-BeF 2 (FNaBe) eutectic salt containing a small amount of ZrF 4 …
Mo-doping for improving the ZrF4 coated-Li[Li0.20Mn0
2018年10月30日 · It implies the ZrF 4 coating layer can restrain the release of oxygen from the Li 2 MnO 3 phase and enhance the intercalation/de-intercalation reversibility of lithium ion. …
Mechanochemical synthesis of fluoride-ion conducting glass and …
2024年4月16日 · In this study, we applied the MC method to synthesize fluoride glasses, followed by the preparation of fluoride glass–ceramics by heat-treating the glasses. ZrF 4 –BaF 2 …
Raman Spectroscopy on Ionic Structure of LiF-ZrF<sub>4</sub> …
The Raman spectroscopy and quantum chemistry calculations were employed to analyze the ionic structure and variation rule of the LiF-ZrF 4 molten salt system with the molar fraction of …
In Situ Experimental Evidence for a Nonmonotonous Structural …
We propose in this paper an original approach to study the structure of the molten LiF−ZrF4 system up to 50 mol % ZrF4, combining high-temperature nuclear magnetic resonance (NMR) …
(PDF) Structure Analysis of LiF-NaF-ZrF4 Molten Salts with Deep ...
2022年6月1日 · To examine ion solvation, exchange, and speciation for minority components in molten salts (MS) typically found as corrosion products, we propose a multimodal approach …
Title: Short to Intermediate-range Structure , Transport , and ...
2022年2月7日 · Abstract: LiF-NaF-ZrF4 multicomponent molten salts are identified as promising candidates for coolant salts in molten salt reactors and advanced high-temperature reactors. …
In this study, we applied the MC method to synthesize fluoride glasses, followed by the preparation of fluoride glass–ceramics by heat-treating the glasses. ZrF4–BaF2 glasses with …
A new preparation route for high purity ZrF4 - ScienceDirect
1992年1月1日 · Generally, the preparation of high purity ZrF4 relies on ZrOC12 systems and the following procedure [1-3]: (1) recrystallization and filtration, (2) solvent extraction or ion …
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