
Stryker's reagent - Wikipedia
Stryker's reagent is a mildly hydridic reagent, used in homogeneous catalysis of conjugate reduction reactions of enones, enoates, and related substrates. The compound is prepared by adding sodium trimethoxyborohydride to a solution of [PPh 3 CuCl] 4 in DMF, after which it precipitates out as a DMF complex ( [HCu (PPh 3)] 6 •DMF). [2] .
RCSB PDB - 3CUH: Cellulomonas fimi Xylanase/Cellulase Cex (Cf …
2008年4月16日 · Biological assembly 1 assigned by authors and generated by PISA (software)
六氢化六 (三苯基膦)六铜 - 维基百科,自由的百科全书
六氢化六 (三苯基膦)六铜 是一种 配位化合物,化学式为C 108 H 96 Cu 6 P 6,可简写为 (PPh 3 CuH) 6,其中Ph表示苯基。 它和三氟甲氧基三氟乙烯共同作用,可用于有机合成引入含氟基团。
Copper hydride - Wikipedia
Copper hydride is an inorganic compound with the chemical formula CuH n where n ~ 0.95. [3] It is a red solid, rarely isolated as a pure composition, that decomposes to the elements. [4] Copper hydride is mainly produced as a reducing agent in organic …
3CUH: Cellulomonas fimi Xylanase/Cellulase Cex (Cf Xyn10A) in …
Exo-beta-1,4-glucanase (3R,4R,5R)-3-hydroxy-5- (hydroxymethyl)piperidin-4-yl 4-O-beta-D-glucopyranosyl-beta-D-glucopyranoside
氢化亚铜 - 维基百科,自由的百科全书
氢化亚铜 (化学式:CuH)是铜的二元氢化物。 Cu-H键很弱因此这种化合物是不稳定的。 [2][3] 硫酸铜 与 次磷酸钠 在少量硫酸存在的条件下反应得到这种红色沉淀。 它受热就分解为金属铜和氢气。 X射线衍射实验已经测定了它的晶体结构。
Structural and elastic properties of Mg3CuH0.6 ternary hydride …
2018年3月1日 · In the Mg–Cu–H system, a novel ternary hydride (Mg 3 CuH 0.6) has been synthesized recently, by a new method based on the direct reaction starting from mixtures of MgH 2 and Cu under high-pressure and moderate-temperature conditions [3].
Structural and elastic properties of Mg 3 CuH 0.6 ternary hydride …
摘要在本工作中,我们研究了新型金属间氢化物化合物Mg 3 CuH 0.6的结构和弹性性能。 已经基于密度泛函理论(DFT)在局部密度逼近(LDA)和广义梯度逼近(GGA)中进行了理论研究。
(Triphenylphosphine)copper hydride hexamer 90 33636-93-0
A structural, spectroscopic, and computational investigation of Stryker's reagent, [HCu {P (C6H5)3}]6, and its isotopomers has provided new insights into the complex. Neutron diffraction shows that the hydrides are best described as edge bridging rather than face bridging. The combination of infrared
从头开始对CH <sub>3</sub> CuH氢化甲基铜的结构和振动频率 …
CH 3 CuH的最佳几何构型和谐波频率是从头算到Hartree-Fock级别使用基价设置为三重Zeta质量的基础集计算得出的。 通过使用大规模CI计算,已经包括了相关效应。