Metal amides (systematic name metal azanides) are a class of coordination compounds composed of a metal center with amide ligands of the form NR 2−. Amido complexes of the …

Solvent-Dependent Switch of Ligand Donor Ability and Catalytic Activity of Ruthenium(II) Complexes Containing Pyridinylidene Amide (PYA) N-Heterocyclic Carbene Hybrid Ligands. …

3 天之前 · Amide groups of peptide backbone are very weak acids. The special character of bismuth has only been truly appreciated in the past 25 years. Find out more in our inorganic …

2006年11月27日 · Coordinating anions: The coordination chemistry of anions with amide-based ligands is described on the basis of crystallographic data for simple anions of five different …

2002年11月1日 · Polydentate amido ligands have recently been widely employed in the coordination chemistry of the early transition metals and the heavy p-block elements. Formally, …

2023年1月23日 · Amide ligands, such as benzamide and sulfonamide, substantially facilitate the processes leading to a carbocation intermediate, which subsequently reacts with nucleophilic …

2010年10月15日 · This work reports the synthesis, structural characterization, and properties of a new six-coordinate nickel(II) complex coordinated by an azo-containing deprotonated pyridine …

2024年3月26日 · We introduce a mild method for the ligand-promoted copper-catalyzed coupling of 2-halophenol to construct DBDO using cost-effective copper salts, ligands, and alkaline …

2024年3月19日 · Bulky amide ligands, like N (SiMe 3) 2, or the even bulkier N (SiPh x Me 3–x) 2, have played a pivotal role in the development of main group chemistry 1 and were shown to …

1998年3月1日 · Structural changes to the amide ligand following metalation that were examined include the C a O and C a –N bond lengths as well as the angles subtended at the carbonyl …