原子转移自由基聚合( ATRP，Atomic transfer radical polymerization) 是可逆失活自由基聚合的一个例子。 与其对应物ATRA或原子转移自由基加成一样，ATRP 是一种利用 过渡金属催化剂 …

Atom transfer radical polymerization (ATRP) is an example of a reversible-deactivation radical polymerization. Like its counterpart, ATRA, or atom transfer radical addition, ATRP is a means …

AGET ATRP initiation systems are similar to SR&NI ATRP in that it starts with (pseudo)alkyl halides as initiators and transition metal complexes in their oxidatively stable state (e.g., Cu II …

2025年1月9日 · Atom transfer radical polymerization (ATRP) is a synthetic method that harnesses radical polymerization to yield well-defined polymers of controlled architecture...

2021年10月18日 · Reversible addition–fragmentation chain-transfer (RAFT) polymerization and atom transfer radical polymerization (ATRP) are the two most common controlled radical...

2022年11月9日 · Atom transfer radical polymerization (ATRP) is one of the most powerful methods to prepare well-defined (co)polymers. Cu-catalyzed ATRP methods are most …

A commonly used chemical reducing agent, ascorbic acid, can be used in both AGET and ARGET ATRP. SR&NI and ICAR ATRP generally differ in the amount of catalyst used and in the rate …

2024年5月15日 · Atom transfer radical polymerization (ATRP) is one of the most often used controlled radical polymerization techniques. It employs very small amounts (ppm) of Cu …

摘要 arget atrp可将反应中催化剂用量降至ppm级,是目前最具工业化应用前景的原子转移自由基聚合(atrp)之一。综述了arget atrp的反应机理、引发剂、催化体系、还原剂、反应条件及其在污 …

摘要 介绍了可以实现活性聚合的ATRP、RATRP、AGET ATRP和ARGET ATRP 4种原子转移自由基聚合的机理,综述了原子转移自由基聚合技术在合成两亲性嵌段共聚物、接枝聚合物和星型 …