The preparation of functionalized graft copolymers utilizing a combination of ATRP, ROMP, thio-bromo and Huisgen-type click chemistries is described. The construction of these polymeric architectures hinges on the use of a norbornene-based -bromo ester that can act as an ATRP

2021年10月18日 · Reversible addition–fragmentation chain-transfer (RAFT) polymerization and atom transfer radical polymerization (ATRP) are the two most common controlled radical polymerization methods. Both...

2002年9月16日 · In atom-transfer radical polymerization (ATRP) multi-halo compounds are used as cores (compound 7 might be used to initiate ATRP directly). These have been prepared from multi-hydroxy compounds by reaction with appropriate acid bromides 10 …

2013年9月1日 · Atom transfer radical polymerization (ATRP) was used as CRP technique to copolymerize NAllAm with NiPAm. For functionalization of the pendant double bonds of the resulting copolymers the thiol–ene reaction was used to couple 2,3,4,6-tetra- O -acetyl-1-thio- β - d -gluco- and -galactopyranoside to the copolymers, followed by deprotection of ...

Starting from a single initiator/monomer/click partner, functionalized graft copolymers are prepared by combining ATRP, ROMP, and thio‐bromo click chemistry. The resulting materials can then be further modified utilizing both traditional copper‐catalyzed and …

Combining ATRP and ROMP with Thio‐Bromo, Copper‐Catalyzed, and Strain‐Promoted Click Reactions for Brush Copolymer Synthesis Starting from a Single Initiator/Monomer/Click Partner Abstract

Semantic Scholar extracted view of "Combining ATRP and ROMP with Thio‐Bromo, Copper‐Catalyzed, and Strain‐Promoted Click Reactions for Brush Copolymer Synthesis Starting from a Single Initiator/Monomer/Click Partner" by C. Hobbs et al.

2019年2月14日 · This contribution describes our recent efforts geared toward the use of a general, thio-bromo “click” reaction as a post-polymerization method for the preparation of flame-resistant polymeric ...

2025年1月9日 · Atom transfer radical polymerization (ATRP) is a synthetic method that harnesses radical polymerization to yield well-defined polymers of controlled architecture...

2019年2月14日 · The preparation of functionalized graft copolymers utilizing a combination of ATRP, ROMP, thio‐bromo, and Huisgen‐type click chemistries is described. The construction of these polymeric architectures hinges on the use of a norbornene‐based α‐bromo ester that can act as an ATRP initiator and ROMP monomer (a so‐called inimer ), as ...