In hydrolysis and electro-oxidation of the borohydride anion BH4−, key reactions in the field of energy, one critical short-living intermediate is BH3OH−. When water was used as both …

2022年3月18日 · In hydrolysis and electro-oxidation of the borohydride anion BH4−, key reactions in the field of energy, one critical short-living intermediate is BH3OH−. When water was used …

2009年3月9日 · We report here boron-11 and hydrogen NMR measurements of the lifetime of BH 4 units in molten LiBH 4, with respect to hydrogen exchange. A well-resolved 11 B pattern of …

To study the reorientational motion of BH 4 groups in β and γ phases of Mg (BH 4) 2 and in α and β phases of Ca (BH 4) 2, we have performed nuclear magnetic resonance (NMR) …

2007年9月1日 · A new, fast, one-pot method of sodium/potassium hydroxyborohydride preparation is presented, along with the 1 H NMR spectrum of hydroxyborohydride, recorded …

To study the reorientational motion of the BH4 groups in RbBH4 and CsBH4, we have performed nuclear magnetic resonance (NMR) measurements of the 1H and 11B spin–lattice relaxation …

This review describes the electrochemical behaviour of borohydride (BH4−) and metaborate (BO2−) anions in alkaline solutions.

2021年9月14日 · 介绍了一种不同的核磁共振 (NMR) 弛豫方法，用于轻金属硼氢化物中 BH 4四面体的旋转运动。 以前的 NMR 弛豫研究主要使用基于四极相互作用下自旋的自旋-晶格弛豫的 …

Tautomerism in the liquid phase (NMR studies) resolves certain apparent conflicts with solid phase X-ray studies. The relationship between the boron nuclear quadrupole moment and the …

2022年3月18日 · When water was used as both solvent and reactant, only BH 3 OH - is detected by 11 B NMR. By moving away from such conditions and using DMF as solvent and water as …