
Highly Active Bipyridine-Based Ligands for Atom Transfer Radical ...
2012年3月29日 · A series of 2,2′-bipyridines with 4,4′-substituents (R-bpy) were investigated for atom transfer radical polymerization (ATRP) of methyl acrylate (MA) and methyl methacrylate …
Exploration of the Bulk Atom Transfer Radical Polymerization of …
2013年8月30日 · The bulk ATRP of styrene can be well controlled by optimizing the polymerization conditions such as temperature, initiators, catalysts, and ligands. Using 1-PEBr …
Tandem catalysis of Atom Transfer Radical Polymerization of ...
2021年11月9日 · The novel approach for conducting ARGET ATRP based on simultaneous use of two copper complexes based on tris[2-(dimethylamino)ethyl]amine (Me 6 TREN), 2,2’ …
苯乙烯的原子转移自由基聚合 (ATRP)——一个典型的“活性”/可控 …
2023年8月30日 · 原子转移自由基聚合 (ATRP)是一种重要的“活性”/可控自由基聚合方法,它通过对聚合体系中大量的高反应活性的自由基可逆去活性化,避免了聚合反应中不可逆的链转移、链 …
ABSTRACT: The synthesis of well-defined polystyrene by atom transfer radical polymerization (ATRP) is reported. The effects of temperature, initiators, catalysts, and ligands on styrene …
Use of Yb-based catalyst for AGET ATRP of acrylonitrile to ...
2012年8月1日 · Yb-based catalyst was used for the first time for atom transfer radical polymerization using activators generated by electron transfer (AGET ATRP) of acrylonitrile …
In Situ Investigation of Electrochemically Mediated Surface …
2017年3月28日 · Electrochemically mediated atom transfer radical polymerization (eATRP) initiates/controls the controlled/living ATRP chain propagation process by electrochemically …
原子转移自由基聚合合成含磺酸均聚物和共聚物,Designed …
采用CuBr/bpy(PMDETA)催化剂和1-苯基溴乙烷通过原子转移自由基聚合(ATRP)成功合成了功能明确的聚(对苯基苯乙烯磺酸盐)和聚(对苯基苯乙烯磺酸盐-共聚苯乙烯) (1-PEBr) 在二苯醚 (DPE) …
溶液中6-O-甲基丙烯酰基-1,2; 3,4-二-O-异亚丙基-D-吡喃半乳糖的 …
We demonstrate that the successful ATRP of MAIPGal can be achieved for 2-EBiB/CuBr/bipy and 2-MBP/CuCl/bipy at 60 °C and for 2-EBiB/CuBr/PMDETA at room temperature. The initiation …
Atom transfer radical polymerization and copolymerization of …
2016年6月1日 · We herein report the ATRP of isoprene and the block copolymerization of isoprene with styrene for the synthesis of polyisoprene-b-polystyrene block copolymer (PS-b …