
Gigantic C120 Fullertubes: Prediction and Experimental Evidence …
2022年8月29日 · We report the first experimental characterization of isomerically pure and pristine C120 fullertubes, [5,5] C120-D5d(1) and [10,0] C120-D5h(10766). These new molecules represent the highest aspect ...
Synthesis and X-ray structure of dumb-bell-shaped C120
1997年6月5日 · We now report that this dumb-bell-shaped molecule can be synthesized by a solid-state mechanochemical reaction of C 60 with potassium cyanide. Our X-ray structural analysis shows that the C 4 ring...
The fullerene dimer C120 and related carbon allotropes
2000年1月1日 · Dimerization of C 60 under the solid-state mechanochemical reaction conditions to give C 120 was found to occur in the presence of potassium salts such as KCN, KOH, and KOAc, or of a small amount of alkali metals, or even of organic solid amines such as 4 …
Mechanochemical Synthesis and Characterization of the Fullerene Dimer C120
The bulk synthesis of the [2 + 2] dimer of fullerene C 60 was achieved by the solid-state mechanochemical reaction of C 60 with KCN by the use of a high-speed vibration milling (HSVM) technique. This reaction took place also by the use of potassium salts such as K 2 CO 3 and CH 3 CO 2 K, metals such as Li, Na, K, Mg, Al, and Zn, and organic ...
Raman study of the temperature-induced decomposition of the fullerene ...
2016年6月16日 · Raman spectra of the C 120 crystalline fullerene dimers, synthesized by high-pressure/high-temperature (HPHT) treatment of the C60 fullerite, were measured at ambient and elevated temperatures (T > 130 °C) in order to study the kinetics of their thermal decomposition.
Determination of the Thermal Stability of the Fullerene Dimers C120 ...
2006年8月10日 · We have produced the fullerene dimers C 120, C 120 O, and C 120 O 2 by a high-speed vibration milling technique. The thermal stability of C 120, C 120 O, and C 120 O 2 has been studied in the temperature range 150−350 °C for up to 4 h under vacuum.
Fullerene-C120 - NIST Chemistry WebBook
Fullerene-C120. Formula: C 120; Molecular weight: 1441.2840; CAS Registry Number: 141176-39-8; Information on this page: Gas phase ion energetics data; References; Notes; Options: Switch to calorie-based units
(Invited) Toward the Isolation of Giant C120-C200 Fullertubes
2022年7月7日 · In this presentation, we will discuss our lab's recent progress toward the isolation of segmentally longer fullertubes of higher aspect ratios as we seek to move from C120 fullertubes to C150 fullertubes and beyond.
Gigantic C 120 Fullertubes: Prediction and Experimental Evidence …
2022年8月29日 · We report the first experimental characterization of isomerically pure and pristine C120 fullertubes, [5,5] C120-D5d (1) and [10,0] C120-D5h (10766). These new molecules represent the highest...
Fullerene dimer C120 and related carbon allotropes
2013年7月28日 · Dimerization of C60 under the solid-state mechanochemical reaction conditions to give C120 was found to occur in the presence of potassium salts such as KCN, KOH, and KOAc, or of a small amount...
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