1, 4, 5, 8-naphthalene diimide (NDI)-based MOFs, due to their tunable structures and properties, have shown promising applications in photochromism, photocatalysis, electrocatalysis, …

The computational simulations for electronic properties of cadmium (Cd) coordinated L-alanine NDI ligand (H2-l-ala NDI) based complex are the focus of this research. For the first time, the Cd-NDI complex (monomer) has been produced using water as ...

2023年4月25日 · The computational simulations for electronic properties of cadmium (Cd) coordinated L-alanine NDI ligand (H₂-l-ala NDI) based complex are the focus of this research. For the first time, the Cd-NDI complex (monomer) has been produced using water as the solvent; this is a new approach to sy …

本研究通过使用L-丙氨酸修饰的NDI配体（即N, N′-双 (L-丙氨酸)萘二酰亚胺，AlaNDI），在溶剂热条件下构建了一种新型的Cd-NDI金属有机框架晶体材料（Cd (AlaNDI) (H₂O)]·DMF·H₂O，简称complex 1）。

1,4,5,8-萘二酰亚胺（NDI）基MOF由于其可调节的结构和性能，在光致变色、光催化、电催化、光热治疗等方面显示出广阔的应用前景。 在此，使用L-丙氨酸修饰的NDI配体，即N,N′-双 (L-丙氨酸)萘二亚胺 (AlaNDI)，一种新型Cd-NDI Cd (AlaNDI) (H 2 O)]·DMF·H 2 O（配合物1）是在溶剂热条件下构建的，其结构与之前报道的结构有明显不同。 结构分析表明，配合物1的堆积结构由两个相邻的Cd原子共享两个AlaNDI配体组成，形成双金属结构单元 [Cd 2 O 8 ]。 每个结构单元总共 …

研究团队首次使用水作为溶剂合成了Cd-NDI配合物（单体），这是一种新的合成方法。 研究采用了晶体学和赫什菲尔德分析，以及CAM-B3LYP/LANL2DZ和B3LYP/LANL2MB基组，通过DFT和TD-DFT模拟对Cd-NDI配合物进行了深入的表征。

2022年9月29日 · 在目前的工作中，基于NDI的配合物，即 [Cd 0.5 (NDI) (HBDC)]·H 2 O ( 1 )和一系列构象异构体 { [Cd (NDI) 0.5 (BDC)]·MeCN} n ( 2 ) 是通过改变溶剂条件（H 2 BDC = 对苯二甲酸，NDI = N，N'-双（3-吡啶基羰基肼）-1,4,5,8-萘二亚胺）合成的。

2022年10月10日 · In the present work, NDI-based complexes, namely, [Cd 0.5 (NDI) (HBDC)]·H 2 O (1) and a series of conformational isomers of { [Cd (NDI) 0.5 (BDC)]·MeCN} n (2), were synthesized by varying the solvent conditions (H 2 BDC = terephthalic acid, NDI = N, N '-bis (3-pyridylcarbonylhydrazine)-1,4,5,8-naphthalene diimide).

2022年11月16日 · Herein, we propose a one-step strategy to construct MOFs with high Ln adsorption capacity via increasing the framework soft alkalinity by further introducing appropriate soft N-donor atoms into the rigidity building blocks. A series of MOFs (Cd-PDI-2D, Cd-PDI-3D, and Cd-NDI-3D) are designed with different functional groups.

The Cd-NDI complex, which combines a Cd atom with two H 2 - l -ala NDI wings to promote self-assembly and multilayer manufacturing, had the highest value of µ (5.36 D and 7.86 D).