1990年1月1日 · We found that the CH3I data fitted well to a quadratic expression In [OH]/[OH]o = at 2 + bt + c. The constant b, the slope at the origin, is then taken to be the true value of the …

2013年12月27日 · Direct dynamics simulations and selected ion flow tube (SIFT) experiments were performed to study the kinetics and dynamics of the OH(-) + CH3I reaction versus …

The majority of CH3I + OH– were formed through a direct mechanism. For both CH2I– + H2O and CH3OH + I–, the direct mechanism is overall more important than the indirect mechanisms, …

2001年1月1日 · For example, in a stoichiometric CHJair flame the fastest path for CH3I destruction is shown to be via H-atom attack, followed by OH attack, with lesser roles for O …

Regarding OH + CH3I, several studies have focused on the dynamics of the reaction. Here, high-level quasi-classical trajectory simulations are carried out at four different collision energies on …

考虑到 OH− + CH3I 的 11 种可能途径，在反应性中观察到明显的模式特异性：一般来说，OH− 伸缩和 CH 伸缩的激发对通道的影响最大。 对于 SN2 和质子抽象产物，反应物初始攻角和产物 …

1990年1月1日 · A discharge-flow resonance-fluorescence technique was used to study the rates of the reactions CH 3 I + OH → products (1) CF 3 I + OH → CF 3 + HOI. (2) Reaction (1) was …

A flash photolysis resonance fluorescence technique has been employed to investigate the kinetics and mechanism of the reaction of OH (X 2 Π) radicals with CH 3 I over the …

2013年12月11日 · Calculations were performed with the OH – quantum number J equal to 0, 3, and 6 to investigate the effect of OH – rotational excitation on the OH – + CH 3 I reaction …

2015年2月5日 · The work presented here gives a detailed picture of the [CH3--I--OH](-) dissociation dynamics and is very important for unraveling the role of [CH3--I--OH](-) in the …