
A kinetic study of the reactions of OH with CH3I and CF3I
1990年1月1日 · We found that the CH3I data fitted well to a quadratic expression In [OH]/[OH]o = at 2 + bt + c. The constant b, the slope at the origin, is then taken to be the true value of the …
Temperature dependence of the OH(-) + CH3I reaction kinetics ... - PubMed
2013年12月27日 · Direct dynamics simulations and selected ion flow tube (SIFT) experiments were performed to study the kinetics and dynamics of the OH(-) + CH3I reaction versus …
Direct Dynamics Simulation of Dissociation of the [CH3--I--OH]− …
The majority of CH3I + OH– were formed through a direct mechanism. For both CH2I– + H2O and CH3OH + I–, the direct mechanism is overall more important than the indirect mechanisms, …
Computational studies of the reactions of CH3I with H and OH
2001年1月1日 · For example, in a stoichiometric CHJair flame the fastest path for CH3I destruction is shown to be via H-atom attack, followed by OH attack, with lesser roles for O …
Regarding OH + CH3I, several studies have focused on the dynamics of the reaction. Here, high-level quasi-classical trajectory simulations are carried out at four different collision energies on …
OH− + CH3I 多通道反应动力学中的振动模式特异性 - X-MOL
考虑到 OH− + CH3I 的 11 种可能途径,在反应性中观察到明显的模式特异性:一般来说,OH− 伸缩和 CH 伸缩的激发对通道的影响最大。 对于 SN2 和质子抽象产物,反应物初始攻角和产物 …
A kinetic study of the reactions of OH with CH3I and CF3I
1990年1月1日 · A discharge-flow resonance-fluorescence technique was used to study the rates of the reactions CH 3 I + OH → products (1) CF 3 I + OH → CF 3 + HOI. (2) Reaction (1) was …
Kinetic study of the reaction of OH with CH3I revisited
A flash photolysis resonance fluorescence technique has been employed to investigate the kinetics and mechanism of the reaction of OH (X 2 Π) radicals with CH 3 I over the …
Temperature Dependence of the OH– + CH3I Reaction Kinetics ...
2013年12月11日 · Calculations were performed with the OH – quantum number J equal to 0, 3, and 6 to investigate the effect of OH – rotational excitation on the OH – + CH 3 I reaction …
Direct dynamics simulation of dissociation of the [CH3--I--OH] …
2015年2月5日 · The work presented here gives a detailed picture of the [CH3--I--OH](-) dissociation dynamics and is very important for unraveling the role of [CH3--I--OH](-) in the …