
d-Band center modulating of CoOx/Co9S8 by oxygen
2022年1月1日 · The partial densities of states (pDOS) for Co 3 O 4 (Fig. S1) shows that the valence band maximum (VBM) and conduction band minimum (CBM) are mainly dominated by Co 3d and O 2p orbits, indicating that transition metal d orbits play a …
Monodisperse Co9S8 nanoparticles in situ embedded within N, S …
2018年7月27日 · Benefiting from the unique honeycomb composite structure composed of monodisperse Co 9 S 8 nanoparticles in situ embedded within the three-dimensional interconnected network carbon matrix with...
A bimetallic sulfide Co9S8/MoS2/C heterojunction in a three …
2023年6月1日 · We report the formation of flower-like Co9S8/MoS2/C composites by a simultaneous vulcanization-carbonization process using MoCl5 as the Mo source and a 2-methylimidazole cobalt salt as the Co and C precursor at different temperatures (600, 700 and 800 ℃) in sublimed sulfur.
Development of Inverse‐Opal‐Structured Charge‐Deficient Co9S8…
2024年1月24日 · An inverse-opal-structured cobalt sulfide@nitrogen-doped-carbon (Co9S8@NC) is developed as a catalytic host of the iodine electrode, specifically targeting improved reaction kinetics for the two-elec...
Three-dimensional nanoflower-like transition metal sulfide ...
2025年2月1日 · In this research, a three-phase transition metal sulfide nanoflower (Co 9 S 8 /Co 1-x S/WS 2) was designed and used as a bifunctional oxygen electrocatalyst. The structure of transition metal sulfides was optimized by modulating the sulfidation temperature, which enhanced the electrocatalytic performance of the catalysts for oxygen.
Charge Self‐Regulation of Metallic Heterostructure Ni2P@Co9S8 …
The metallic Ni2P@Co9S8 heterostructure is a highly efficient and stable bifunctional catalyst for overall water splitting. The electron transfer from Co─Co bonds of Co9S8 to active Ni sites of Ni2P ...
CoP/Fe‐Co9S8 for Highly Efficient Overall Water Splitting with …
2022年10月21日 · The d-band partial density of states (PDOS) of Co atoms in CoO 2 /Fe-Co 9 S 8 and the p-band PDOS of O atoms were analyzed to predict the adsorption intensity of oxygen intermediate species in the OER process (Figure 4a).
(a, b) pDOS of the Co 9 S 8 (100) stoichiometric ... - ResearchGate
Figures 8 and 9 show the projected density of states (pDOS) of surface cobalt and sulfur atoms in the stoichiometric slabs, together with the crystal orbital overlap population (COOP) analysis.
同步辐射技术揭示Co9S8@Fe3O4在碱性水氧化反应中的结构演变
本工作利用水热法成功构建具有优异电化学活性的Co9S8@Fe3O4异质结构催化剂。研究结果表明,得益于Fe3O4发挥的“栅栏”作用,在OER过程中Co9S8组分经历了Co9S8→CoOx→CoOOH的重构过程,但是整个催化剂三维形貌结构并未发生坍塌。
In situ anchoring of Co9S8 nanoparticles on N and S co-doped …
2016年9月9日 · Here we report Co 9 S 8 nanoparticles grown in situ on nitrogen- and sulfur-doped porous carbon (Co 9 S 8 /NSPC) as a bifunctional catalyst for OER and ORR using poly (2-aminothiazole) as a...