Flavin adenine dinucleotide - Wikipedia
In biochemistry, flavin adenine dinucleotide (FAD) is a redox -active coenzyme associated with various proteins, which is involved with several enzymatic reactions in metabolism. A …
Calculating Chemically Accurate Redox Potentials for Engineered ...
2008年10月2日 · The tricyclic isoalloxazine nucleus of the redox cofactors flavin mononucleotide (FMN) and flavin adenine dinucleotide (FAD) acts as an electron sink in life-sustaining …
Quantum theory of a potential biological magnetic field sensor: Radical …
2024年12月1日 · Recent studies in vitro and in vivo suggest that flavin adenine dinucleotide (FAD) on its own might be able to act as a biological magnetic field sensor. Motivated by these …
EPR spectroscopy on flavin radicals in flavoproteins
2019年1月1日 · In detail, the neutral FAD radical of Escherichia coli CPD photolyase (EcPL) (Fuchs et al., 2002) is compared with anionic and neutral flavin radicals of Aspergillus niger …
Hydrogen-bond switching through a radical pair mechanism in a ... - PNAS
2006年7月18日 · We show that formation of the red-shifted signaling state proceeds by means of a radical-pair mechanism, driven by ET and PT processes to FAD from its protein environment …
How much do you really know the FAD? - University of …
FAD or flavin adenine dinucleotide is a very common coenzyme (a cofactor made up of organic molecules) in proteins. Similar to NAD and NADP in that it carries electrons, FAD participates …
Radical-based photoinactivation of fatty acid photodecarboxylases
2020年7月1日 · Fatty acid photodecarboxylases (FAP) are a recently discovered family of FAD-containing, light-activated enzymes, which convert fatty acids to n-alkanes/alkenes with …
Flavin Adenine Dinucleotide Photochemistry Is Magnetic Field …
We present time-resolved optical absorption and magnetic field effect data on the photochemistry following blue light excitation of flavin adenine dinucleotide (FAD) in aqueous solution in the …
Ultrafast dynamics of flavins in five redox states - PMC
In this work, we systematically examine the excited-state dynamics of five redox states of flavins from oxidized FAD and FMN, to anionic radical FAD •-, to neutral radical FMNH •, to fully …
Magnetic field effects as a result of the radical pair mechanism are ...
Subsequent long-range, interdomain electron transfer between FAD and flavin mononucleotide (FMN) generates di-radical flavin semiquinone states that form/decay on the (ms–s) timescale. …