2009年7月14日 · This study represents the first detection and identification of an unusual carbon-centered quinone ketoxy radical, which provides direct experimental evidence to further support and expand our previously proposed mechanism for metal-independent decomposition of hydroperoxides by halogenated quinones.

2013年7月21日 · We found, unexpectedly, that the radical form of the carbon-centered quinone ketoxy radical adduct with a recently developed spin-trapping agent BMPO can not only be directly detected and identified using HPLC/high resolution MS, but can also be isolated and purified using semi-preparative HPLC, ena …

2007年11月6日 · This study represents the first detection and identification of an unusual carbon-centered quinone ketoxy radical, which provides direct experimental evidence to further support and expand the previously proposed mechanism for metal-independent decomposition of hydroperoxides by halogenated quinones.

2013年10月1日 · The lipid alkoxyl radical 13-LO is a relatively reactive radical, so not only will it react with quinone ketoxy radical to form conjugates, but the transfer of radical center and cleaving of adjacent C–C bonds may also lead to the generation of various long-chain lipid acids (Supplementary Scheme S2).

2013年5月28日 · We found, unexpectedly, that the radical form of the carbon-centered quinone ketoxy radical adduct with a recently developed spin-trapping agent BMPO can not only be directly detected and identified using HPLC /high resolution MS, but can also be isolated and purified using semi-preparative HPLC, enabling direct observation of its clean 6-line ...

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2015年5月18日 · In summary, these findings demonstrated that XQ can facilitate ROOH decomposition to produce reactive alkoxyl, quinone ketoxy, lipid alkyl radicals, and genotoxic HNE via a novel metal-independent mechanism, which may explain partly their potential genotoxicity and carcinogenicity.

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The First Purification and Unequivocal Characterization of the Radical Form of the Carbon-centered Quinone Ketoxy Radical Adduct Chun-Hua Huang,a Guo-Qiang Shan,a Li Mao,a Balaraman Kalyanaraman,c Hao Qin,a Fu-Rong Rena and Ben-Zhan Zhu*a,b

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