
Enabling reversible redox reactions in electrochemical cells …
The x-ray diffraction (XRD) peaks in Fig. 1A provide immediate information about the composition of LiAl alloy. The XRD pattern indicates that Li and the Li 9 Al 4 intermetallic compound are the dominant species present and that the crystal structures correspond to Li …
Carbon-free and binder-free Li-Al alloy anode enabling an all …
2022年4月13日 · In situ x-ray diffraction (XRD) was adopted to investigate the lithiation process of Al and unveiled a two-phase reaction with modest volume change. The appropriate operating potential and temperate volume change of Li-Al alloy resulted in its excellent stability toward LGPS, as proven by the electrochemical test of symmetric cells and ...
Physical characterizations of the LiAl anode. (A) XRD profile of the ...
The x-ray diffraction (XRD) peaks in Fig. 1A provide immediate information about the composition of LiAl alloy. The XRD pattern indicates that Li and the Li 9 Al 4 intermetallic...
Lithium adsorption properties of porous LiAl-layered double …
2022年9月1日 · The LiAl-LDHs were characterized by Fourier transform infrared spectroscopy (FT-IR), powder X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and porosity. Special attention was focused on the rise of Li+ adsorption capacity based on the porous morphology in synthetic and real salt lake brine.
Thermal Evolution of the Cl-−LiAl2 Layered Double Hydroxide: A ...
2001年10月30日 · The combination of XRD, TG/DSC, and compositional analysis with 27Al, 6Li, 7Li, and 35Cl NMR spectroscopy at a high field (H0 = 17.6 T) provides a comprehensive picture of the phase formation, phas...
何平/周豪慎教授Science Advances:全固态锂硫电 …
图2C为LiAl合金电极的原位XRD图谱,从图中可以看出,随着锂化过程,LiAl峰逐渐出现,且强度逐渐增加,与Al峰共存直至结束。 表明,Li0.8Al合金是Al和LiAl的两相混合物,Al:LiAl = 1:4。
In-Situ Characterization of the Li-Al System at Elevated …
2019年6月30日 · We will present ex- and in-situ (variable temperature cycling, room temperature XRD, with and without cell disassembly) and in-operando (integrated variable temperature cycling and XRD, without cooling) results from aluminum thin films and (much thicker, but still thin) aluminum foils to map out phase formation as a function of temperature, samp...
Enhanced Defluoridation Using Novel Millisphere Nanocomposite …
2018年8月6日 · In our recent study 16, a nanocomposite LiAl-LDH@201 with enhanced stability (over pH 3.5–12) and improved fluoride removal capacity was developed by impregnating Li/Al LDHs into a millimetric...
锂铝水滑石样化合物吸附Cu <sup>2+</sup>和Zn <sup>2
X射线衍射(XRD),傅立叶变换红外光谱(FTIR),扫描电子显微镜(SEM)和透射电子显微镜(TEM)表征显示了Li Al HTlc的相互连接的花状层状结构。 在给定的吸附剂浓度(C s)下,Cu 2+ 和Zn 2+ 在Li Al HTlc上的吸附动力学和等温线分别与拟二级模型和Langmuir模型一致。 该 ç 观察到 s 对吸附动力学和等温线的影响,Langmuir-表面组分活度(SCA)方程可用于表征 C s 在吸附等温线中的作用。 吸附过程是自发的,并且是吸热的。 吸附机理表明吸附过程是通过两种 …
铝酸锂在700°C下的还原和氧化气氛中的稳定性 - X-MOL
研究了铝酸锂(LiAlO 2)粉末在700℃还原(4%H 2 N 2)和氧化(空气)气氛下的稳定性。XRD结果显示原始的α- LiAlO 2样品包含少量LiAl 2(OH)7 ·2H 2 O和LiAlO 2 ·0.25H 2 O相,而高温XRD研究表明LiAl 2(OH)7 · 2H 2 O在700°C时可能分解为γ- LiAlO 2和LiAlO 2 ·0.25H 2 O分解 …