
A Highly Stable Porphyrinic Zirconium Metal–Organic …
2014年12月5日 · With its extremely high connectivity, PCN-223 shows high stability in aqueous solutions with a wide range of pH. Cationic PCN-223(Fe) formed by postsynthetic treatment is an excellent recyclable heterogeneous catalyst for the hetero-Diels–Alder reaction.
Study of Electrocatalytic Properties of Metal–Organic Framework PCN-223 …
2017年3月29日 · A highly robust metal–organic framework (MOF) constructed from Zr6 oxo clusters and Fe(III) porphyrin linkers, PCN-223-Fe was investigated as a heterogeneous catalyst for oxygen reduction reaction ...
A Porphyrinic Zirconium Metal–Organic Framework for Oxygen …
2020年8月10日 · We prepared PCN-226 nanocrystals to improve the diffusion kinetics of adsorbed and reacting molecules. The structure of PCN-226 was determined by continuous rotation electron diffraction (cRED), also known as microcrystal electron diffraction (MicroED).
PCN-223 as a drug carrier for potential treatment of colorectal cancer
2020年4月25日 · We propose that PCN-223 nanoparticles, a kind of MOF, may be used as potential carriers for drug delivery to the rectum for the treatment of CRC. The PCN-223 nanoparticles possess a highly porous structure, into which an anti-cancer drug, such as 5FU, can be encapsulated to serve as a depot for sustained drug release.
Porphyrinic metal-organic frameworks for biological applications
2023年3月1日 · PCN-223 was camouflaged with phospholipid bilayers to improve the biostability and cellular uptake owing to the strong Zr–O–P chemical complexation between Zr-MOFs and phospholipid [37].
Zr6O8-porphyrinic MOFs as promising catalysts for the boosting ...
2022年7月15日 · In previous work, we demonstrated that Zr 6 O 8 -porphyrin-like MOFs (PCN-223) not only possess good ability to remove pollutants, but also resist the interference from high salt ions during the catalytic process due to the ·OH …
A highly stable porphyrinic zirconium metal-organic framework ... - PubMed
2014年12月24日 · With its extremely high connectivity, PCN-223 shows high stability in aqueous solutions with a wide range of pH. Cationic PCN-223 (Fe) formed by postsynthetic treatment is an excellent recyclable heterogeneous catalyst for the hetero-Diels-Alder reaction.
Light harvesting and energy transfer in a porphyrin-based metal …
We present the synthesis and photophysical characterization of a water stable PCN-223 (freebase) metal organic framework (MOF) constructed from meso -tetrakis (4-carboxyphenyl)porphyrin (TCPP).
A Highly Stable Porphyrinic Zirconium Metal–Organic Framework …
2014年12月24日 · With its extremely high connectivity, PCN-223 shows high stability in aqueous solutions with a wide range of pH. Cationic PCN-223(Fe) formed by postsynthetic treatment is an excellent recyclable heterogeneous catalyst for the hetero-Diels–Alder reaction.
Study of Electrocatalytic Properties of Metal-Organic Framework PCN-223 …
2017年10月4日 · A highly robust metal-organic framework (MOF) constructed from Zr 6 oxo clusters and Fe(III) porphyrin linkers, PCN-223-Fe was investigated as a heterogeneous catalyst for oxygen reduction reaction (ORR). Films of the framework were grown on a conductive FTO substrate and showed a high cat …