2013年10月14日 · A series of highly stable MOFs with 3-D nanochannels, namely PCN-224 (no metal, Ni, Co, Fe), have been assembled with six-connected Zr 6 cluster and metalloporphyrins by a linker-elimination strategy.

2018年10月17日 · PCN-224 nanoparticles are hydrothermally synthesized by coordinating tetra-kis (4-carboxyphenyl)porphyrin (TCPP) ligands with zirconium. The PCN-224 nanoparticles show high photo-oxygenation efficiency, good biocompatibility, and high stability.

2021年5月25日 · We propose disordered PCN-224 (d PCN-224) as a unified model to understand PCN-221, MOF-525, and PCN-224 by varying the degree of orientational cluster disorder, linker conformation and...

The results showed that FA-modified PCN-224 NMOFs had better cellular uptake by FAR-positive Hela cells than PCN-224 NMOFs due to the FA receptor-mediated endocytosis, and further improved PDT efficacy against Hela cells.

2021年6月2日 · Porphyrin-based PCN-224 NPs are synthesized as a sonosensitizer with a large amount of well-organized porphyrin molecules while simultaneously acting as the nanocarriers (NCs) for Pt NPs and GOx.

2018年10月31日 · PCN-224 nanoparticles are hydrothermally synthesized by coordinating tetra-kis (4-carboxyphenyl)porphyrin (TCPP) ligands with zirconium. The PCN-224 nanoparticles show high photo-oxygenation efficiency, good biocompatibility, and high stability.

2013年11月13日 · A series of highly stable MOFs with 3-D nanochannels, namely PCN-224 (no metal, Ni, Co, Fe), have been assembled with six-connected Zr6 cluster and metalloporphyrins by a linker-elimination strategy.

2024年2月9日 · Here, we present a simple, fast, and efficient synthesis of core@shell NCs that occur at mild conditions, i.e., room temperature (RT) and short reaction time (1 h). These NCs comprise a gold bipyramid (AuB) NP as core and PCN-224 Zr-porphyrinic NMOF as shell (Figure S1, Supporting Information).

In this study, a photocatalytic antibacterial and anticancer agent, Bi NPs/PCN-224, was synthesized by doping Bi NPs in PCN-224, obtained through hydrothermal process of porphyrin, using benzoic acid as a morphology modifier.

Herein, different-sized porphyrinic metal–organic frameworks (MOFs), PCN-224 (90, 125, and 200 nm), were developed via the coordination of tetra-kis (4-carboxyphenyl) porphyrin (TCPP) and the metal zirconium to enhance the local delivery of porphyrins, and fluorescent sonosensitizers (methylene blue or rhodamine 6G) were further incorporated ...