Cl 2 adds to PPh 3 to give triphenylphosphine dichloride ( [PPh 3 Cl]Cl), which exists as the moisture-sensitive phosphonium halide. This reagent is used to convert alcohols to alkyl chlorides in organic synthesis.

Efficient synthesis of β-enaminones and β-enaminoesters catalyzed by gold (I)/silver (I) under solvent-free conditions. An efficient method for the synthesis of β-enaminones and β-enaminoesters using a combination of [ (PPh (3))AuCl]/AgOTf as catalyst has been developed.

Phenoxide-assisted P-C bond cleavage in PdCl2 (PPh3) 2 under very mild conditions. Modular Synthesis of Phosphino Hydrazones and Their Use as Ligands in a Palladium-Catalysed Cu-Free Sonogashira Cross-Coupling Reaction.

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Bis (triphenylphosphine)palladium chloride is a coordination compound of palladium containing two triphenylphosphine and two chloride ligands. It is a yellow solid that is soluble in some organic solvents. It is used for palladium-catalyzed coupling reactions, e.g. the Sonogashira–Hagihara reaction. The complex is square planar.

Trost group's protocol yields α-vinylsilanes from terminal acetylenes using [Cp*Ru (MeCN)3]PF6 catalyst and others for hydrosilylation.

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Wilkinson's catalyst (chlorido­tris (triphenylphosphine)­rhodium (I)) is a coordination complex of rhodium with the formula [RhCl (PPh 3) 3], where 'Ph' denotes a phenyl group. It is a red-brown colored solid that is soluble in hydrocarbon solvents such as benzene, and more so in tetrahydrofuran or chlorinated solvents such as dichloromethane.

Choose from thousands of catalysts and ligands. Scroll down to find out more about the products below. Color and Form:white pwdr. For product pricing, customization, or other enquiries: Buchwald . Products.

Carbonylchlorohydridotris (triphenylphosphine)ruthenium (II) is a coordination compound commonly used as a catalyst in organic synthesis reactions such as hydrogenation, transfer hydrogenative C-C bond-forming reactions, transfer hydrogenation, and α-alkylation of ketones with primary alcohols.